A typical and environment-friendly fluorescent polyamine-amine (PAMAM) features good compatibility and unique surface modification, while it is restricted by a low fluorescence property performance and an unclear fluorescence mechanism. In this work, we prepared blue fluorescent PAMAM polymer dots (PDs) via a simple hydrothermal method based on dichloromethane (DCM) and 2.0G PAMAM. The quantum yield achieved was 32.1%, which was 25 times stronger than that of 2.0G PAMAM due to the lone-pair electron leap of the amine groups, the aggregation of carbonyl groups, as well as the crosslinking induced by DCM inside the PAMAM. In addition, the fluorescent 2.0G PAMAM-DCM PDs show a great Fe3+ sensing property with the detection limit of 56.6 nM, which is much lower than the safety limits (5.36 μM) in drinking water, indicating its great potential for Fe3+ detection in aqueous media.
ZnO nanosheets decorated with Au nanoparticles by galvanic reduction method and its application in recyclable 3D surface-enhanced Raman scattering substrates.
Photodynamic therapy (PDT) has made important progress in tumor treatment, but it is still limited by the poor light penetration depth, and the negative cycle between hypoxic microenvironment and oxygen...
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