A photocatalytic system containing a perylene bisimide (PBI) dye as a photosensitizer anchored to titanium dioxide (TiO2) nanoparticles through carboxyl groups was constructed. Under solar‐light irradiation in the presence of sacrificial triethanolamine (TEOA) in neutral and basic conditions (pH 8.5), a reaction cascade is initiated in which the PBI molecule first absorbs green light, giving the formation of a stable radical anion (PBI.−), which in a second step absorbs near‐infrared light, forming a stable PBI dianion (PBI2−). Finally, the dianion absorbs red light and injects an electron into the TiO2 nanoparticle that is coated with platinum co‐catalyst for hydrogen evolution. The hydrogen evolution rates (HERs) are as high as 1216 and 1022 μmol h−1 g−1 with simulated sunlight irradiation in neutral and basic conditions, respectively.

A perylene bisimide functionalized with four 4-carboxyphenoxy substituents at bay area (PBI-COOH) was embedded in sol–gel-derived zinc oxide (ZnO) to fabricate organic–inorganic hybrid photoconductive cathode interlayers (ZnO:PBI-COOH) that can be annealed at a rather low temperature of 120–130 °C as desired for plastic substrates for flexible devices. For these interlayers, the structural defects including oxygen vacancy and residual hydroxy groups are reduced that leads to increased electron mobility, and a photoinduced electron transfer from the organic dopant into the conduction band of ZnO endows the hybrid thin film with relatively higher conductivity when compared to the undoped ZnO thin film. The low-temperature-processed hybrid thin films were applied on indium tin oxide electrodes to produce inverted organic solar cells (OSCs) with power conversion efficiencies of 11.68 and 13.48% when using J71:ITIC and PBDB-T-2Cl:IT4F as active layers, respectively. Finally, flexible OSCs are fabricated on poly­(ethylene terephthalate) substrates that maintained stability with relatively high performance after 100 times bending.

Vertical-structure photodetectors usually have the advantages of fast response speed and low driving voltage, but suffer from the high dark current that suppresses the detectivity of the devices. Introducing hole/electron-transporting...

A photocatalytic system containing a perylene bisimide (PBI) dye as a photosensitizer anchored to titanium dioxide (TiO2) nanoparticles through carboxyl groups was constructed. Under solar‐light irradiation in the presence of sacrificial triethanolamine (TEOA) in neutral and basic conditions (pH 8.5), a reaction cascade is initiated in which the PBI molecule first absorbs green light, giving the formation of a stable radical anion (PBI.−), which in a second step absorbs near‐infrared light, forming a stable PBI dianion (PBI2−). Finally, the dianion absorbs red light and injects an electron into the TiO2 nanoparticle that is coated with platinum co‐catalyst for hydrogen evolution. The hydrogen evolution rates (HERs) are as high as 1216 and 1022 μmol h−1 g−1 with simulated sunlight irradiation in neutral and basic conditions, respectively.