Black
orthorhombic (B-γ) CsSnI3 with low toxicity
and excellent optoelectronic properties is a promising candidate for
perovskite solar cell (PSC). However, the performance of the B-γ
CsSnI3-based PSCs is much lower than their lead-based or
organotin-based counterparts due to the heavy self-doping of Sn2+ to form Sn4+ under ambient-air conditions. Here,
this undesirable oxidation in CsSnI3 is restricted by engineering
the localized electron density with phthalimide (PTM) additive. The
lone electron pairs of NH and two CO units of PTM are designed to
form trigeminal coordination bonding with Sn2+, resulting
in reduced defect density and relatively grain-ordered perovskite
film. The champion efficiencies of 10.1% and 9.6% are obtained for
the modified rigid and flexible B-γ CsSnI3-based
PSCs, respectively. These encapsulated devices maintain 94.3%, 83.4%,
and 81.3% of their initial efficiencies under inert (60 days), ambient
(45 days), and 1 Sun continuous illumination at ∼70 °C
(2000 min) conditions, respectively.
Fullerene derivative, such as [6,6]-phenyl C61 butyric acid methyl ester (PCBM), is widely used as an electron-transport layer (ETL) in inverted perovskite solar cell (PSC). However, its low electron mobility, complexity in achieving quality film formation, and severe nonradiative recombination at perovskite/PCBM interface due to the large electron capture region, lead to lower efficiency for inverted PSCs compared to the normal structures. Herein, we demonstrate an effective and practical strategy to overcome these challenges. Conjugated n-type polymeric materials are mixed together with PCBM to form a homogeneous bulk-mixed (HBM) continuous film with high electron mobility and suitable energy level. HBM film is found to completely cap the perovskite surface to enhance the electron extraction. The critical electron capture radius of the HBM decreases to 12.52 nm from 14.89 nm of PCBM due to the large relative permittivity, resulting in reduced nonradiative recombination at perovskite/ HBM interface. The efficiency of inverted PSCs with HBM ETLs exceeds 20.6% with a high fill factor of 0.82. Further, the stability of devices is improved owing to the high hydrophobicity of the HBM ETLs. Under ambient air condition after 45 days, the efficiency of inverted PSCs based on HBM remains 80% of the initial value. This is significantly higher than the control devices which retain only 48% of the initial value under similar aging conditions. We believe these breakthroughs in improving efficiency and stability of inverted PSCs will expedite their transition.
Solution processability of photoactive halide perovskites differentiates them from traditional inorganic semiconducting materials that require multiple post-processing steps such as thermal/vacuum/blow- & solvent-assistant treatment. Here we report a technical breakthrough...
Black
orthorhombic (B-γ) CsSnI3 with reduced biotoxicity
and environmental impact and excellent optoelectronic properties is
being considered as a promising eco-friendly candidate for high-performing
perovskite solar cells (PSCs). A major challenge in a large-scale
implementation of CsSnI3 PSCs includes the rapid transformation
of Sn2+ to Sn4+ (within a few minutes) under
an ambient-air condition. Here, we demonstrate that ambient-air stable
B-γ CsSnI3 PSCs can be fabricated by incorporating N,N′-methylenebis(acrylamide) (MBAA)
into the perovskite layer and by using poly(3-hexylthiophene) as the
hole transporting material. The lone electron pairs of −NH
and −CO units of MBAA are designed to form coordination bonding
with Sn2+ in the B-γ CsSnI3, resulting
in a reduced defect (Sn4+) density and better stability
under multiple conditions for the perovskite light absorber. After
a modification, the highest power conversion efficiency (PCE) of 7.50%
is documented under an ambient-air condition for the unencapsulated
CsSnI3-MBAA PSC. Furthermore, the MBAA-modified devices
sustain 60.2%, 76.5%, and 58.4% of their initial PCEs after 1440 h
of storage in an inert condition, after 120 h of storage in an ambient-air
condition, and after 120 h of 1 Sun continuous illumination, respectively.
Narrowband photodetector (NB‐PD) with selective light detection is critical for artificial vision and imaging. Intrinsic (optical‐filter‐free) NB‐PDs using conjugated organics or halide perovskite materials have been developed for eliminating the current complex filtering systems in NB‐PDs. However, the poor performance and external driving circuit of organic NB‐PDs as well as complex doping and uncontrollable recombination reactions in typical perovskite NB‐PDs have limited their applicational diversification. A p‐type self‐doped perovskite for intrinsic NB detection is reported which exhibits unique unbalanced electron–hole transfer kinetics. In conjunction with the optical field distribution, an unbalanced charge transport within the self‐doped perovskite triggers a wavelength‐dependent photo‐carrier collection, resulting in a novel spontaneous internal quantum efficiency narrowing mechanism. As a result, by reverting the device architectural polarity, an NB detection at a monochromic light of either red or UV is observed. Using such a revertible asymmetric device design, self‐powered NB‐PDs are successfully achieved. Briefly, the corresponding NB‐PDs exhibit excellent narrow response with a response window of ≈100 nm, high detectivity ≈1011 Jones, and fast response speed (f−3dB ≈ 60 kHz) at zero bias. These results demonstrate a new strategy of manipulating internal charge transport to realize power‐free and filter‐free intrinsic NB‐PDs.
Perovskite solar cells (PSCs) without charge-carrier-transport layers (CTLs) are theoretically achievable due to the ambipolar charge-carrier-transfer characteristics presenting in perovskites. However, the power conversion efficiency (PCE) of the CTL-free PSCs needs further improvement. Herein, we provide a breakthrough in the fabrication of the cost-effective high-performance holetransport-layer (HTL)-free PSC and trilayer PSC with device configurations of fluorine doped tin oxide (FTO)/SnO 2 /perovskite/carbon and FTO/perovskite/ carbon, respectively. We introduce perfluorotetradecanoic acid (PFTeDA) with a carbonyl unit and carbon fluorine bonds to suppress the ion migration and reduce the crystal defects in perovskites. The modified carbon-based HTL-free PSC shows a record PCE of 18.9%. Furthermore, the PFTeDA molecules are found existing at the grain boundaries between the perovskite crystals, resulting in enhanced environmental, thermal, and light stabilities for the resultant cost-effective highperformance CTL-free PSCs.
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