Catalytic ozonation is believed to belong to advanced oxidation processes (AOPs). Over the past decades, heterogeneous catalytic ozonation has received remarkable attention as an effective process for the degradation of refractory organics in wastewater, which can overcome some disadvantages of ozonation alone. Metal oxides, metals, and metal oxides supported on oxides, minerals modified with metals, and carbon materials are widely used as catalysts in heterogeneous catalytic ozonation processes due to their excellent catalytic ability. An understanding of the application can provide theoretical support for selecting suitable catalysts aimed at different kinds of wastewater to obtain higher pollutant removal efficiency. Therefore, the main objective of this review article is to provide a summary of the accomplishments concerning catalytic ozonation to point to the major directions for choosing the catalysts in catalytic ozonation in the future.

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