A method based on capacitively coupled contactless conductivity detection (C4D), which has been proven effective for the rapid detection of available soil potassium content, was firstly proposed to apply to soil nutrient detection. By combining a detection signal spectrum analysis, geographic information system (GIS) data, and a cluster analysis, a soil nutrient management system to match the detection device was developed. This system included six modules: soil sample information management, electrophoresis analysis, quantitative calculation, nutrient result viewing, cluster analysis, and nutrient distribution map generation. The soil samples, which were collected from an experimental field in Xuchang City of Henan Province, were analyzed using the C4D and flame photometer methods. The results showed that the detection results for the soil samples obtained via the two methods were in good agreement. C4D technology was feasible for the detection of the soil available nutrients and had the advantages of a high timeliness, low sample volume, and low pollution. The soil nutrient management system adopted the hierarchical clustering method to classify the grid cells of the experimental field according to the nutrient detection results. A soil nutrient distribution map displayed the spatial difference in nutrients. This paper provides a systematic solution for soil nutrient zone management that includes nutrient detection, signal analysis, data management for the nutrient zone, and field nutrient distribution map generation to support decision making in variable fertilization.
In order to alleviate global warming and the energy crisis, it is of great significance to develop and utilize solar energy resources. Sunshine duration (SD) is considered to be the best substitute for solar radiation and a key factor in evaluating solar energy resources. Therefore, the spatial and temporal characteristics of SD and the reasons for its changes have received extensive attention and discussion. Based on the data of 415 meteorological stations from 1970 to 2019, this paper uses linear trend analysis, Mann–Kendall mutation analysis, the Hurst index, empirical orthogonal decomposition, correlation analysis and partial correlation analysis to analyze the spatiotemporal characteristics of SD and its relationship with influencing factors. The results show that the annual SD in China shows a downward trend, with a climate trend rate of −37.93 h/10a, and a significant decline from 1982 to 2019. The seasonal SD shows a downward trend, and the downward trend is most obvious in summer. The annual and seasonal SD will still show a downward trend in the future. The spatial distribution of SD not only has an overall consistent distribution but also takes the Yellow River from Ningxia to Shandong as the boundary, showing a north–south opposite distribution. Annual SD has a significant positive correlation, a significant negative correlation, a positive correlation and a negative correlation with wind speed, precipitation, temperature and relative humidity, respectively, and it is most closely related to wind speed and precipitation. In addition, the change in SD may also be related to human activities.
Ozone is a very important trace gas in the atmosphere, it is like a “double-edged sword”. Because the ozone in the stratosphere can effectively help the earth’s organisms to avoid the sun’s ultraviolet radiation damage, the ozone near the ground causes pollution. Therefore, it is essential to explore the time-frequency domain variation characteristics of total column ozone and have a better understanding of its cyclic variation. In this paper, based on the monthly scale dataset of total column ozone (TCO) (September 2002 to February 2023) from Atmospheric Infrared Sounder (AIRS) carried by NASA’s Aqua satellite, linear regression, coefficient of variation, Mann-Kendall (M-K) mutation tests, wavelet analysis, and empirical orthogonal function decomposition (EOF) analysis were used to analyze the variation characteristics of the TCO in China from the perspectives of time domain, frequency domain, and spatial characteristics. Finally, this study predicted the future of TCO data based on the seasonal autoregressive integrated moving average (SARIMA) model in the time series algorithm. The results showed the following: (1) From 2003 to 2022, the TCO in China showed a slight downward trend, with an average annual change rate of −0.29 DU/a; the coefficient of variation analysis found that TCO had the smallest intra-year fluctuations in 2008 and the largest intra-year fluctuations in 2005. (2) Using the M-K mutation test, it was found that there was a mutation point in the total amount of column ozone in 2016. (3) Using wavelet analysis to analyze the frequency domain characteristics of the TCO, it was observed that TCO variation in China had a combination of 14-year, 6-year, and 4-year main cycles, where 14 years is the first main cycle with a 10-year cycle and 6 years is the second main cycle with a 4-year cycle. (4) The spatial distribution characteristics of the TCO in China were significantly different in each region, showing a distribution characteristic of being high in the northeast and low in the southwest. (5) Based on the EOF analysis of the TCO in China, it was found that the variance contribution rate of the first mode was as high as 52.85%, and its spatial distribution of eigenvectors showed a “-” distribution. Combined with the trend analysis of the time coefficient, this showed that the TCO in China has declined in the past 20 years. (6) The SARIMA model with the best parameters of (1, 1, 2) × (0, 1, 2, 12) based on the training on the TCO data was used for prediction, and the final model error rate was calculated as 1.34% using the mean absolute percentage error (MAPE) index, indicating a good model fit.
Atmospheric visibility is an important indicator that reflects the transparency of the atmosphere and characterizes the air quality, so it is of great significance to study the long-term change in visibility. This paper is based on the global surface summary of day data (GSOD) site dataset and other relevant data, using the Mann–Kendall (MK) mutation point test, wavelet transform, and seasonal autoregressive integrated moving average (SARIMA) model forecasting. The time-frequency domain variation characteristics and related influencing factors of regional visibility in China were studied in detail, and the visibility was predicted; the results of the study showed the following: (1) the overall interannual variation of regional visibility in China has a decreasing trend, and the four-season variation has a decreasing trend, except for the rising trend in summer, with abrupt change points in both the overall interannual variation and the four-season variation. (2) There are main cycles of visibility in the Chinese region with time scales of 180 months and 18 months. Under the time scale of 180 months for the main cycle, the variation period of visibility is about 123 months, experiencing two high to low variations; under the time scale of 18 months for the main cycle, the variation period of visibility is 12 months, experiencing 21 high to low variations. (3) The development of the economy indirectly affects changes in visibility. Cities with high economies are densely populated, with concentrations of various particulate emissions and high concentrations of particulate matter, which can directly reduce visibility. (4) Two prediction models, SARIMA and long and the short-term memory (LSTM) neural network, were used to predict the visibility in China, both of which achieved good evaluation indexes, and the visibility in China may show an increasing trend in the future.
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