Metal-organic frameworks (MOFs), with their well-defined pores and rich structural diversity and functionality, have drawn a great deal of attention from across the scientific community. However, industrial applications are hampered by their intrinsic fragility and poor processability. Stable and resilient MOF devices with tunable flexibility are highly desirable. Herein, we present a solvent- and binder-free approach for producing stable MOF coatings by a unique hot-pressing (HoP) method, in which temperature and pressure are applied simultaneously to facilitate the rapid growth of MOF nanocrystals onto desired substrates. This strategy was proven to be applicable to carboxylate-based, imidazolate-based, and mixed-metal MOFs. We further successfully obtained superhydrophobic and "Janus" MOF films through layer-by-layer pressing. This HoP method can be scaled up in the form of roll-to-roll production and may push MOFs into unexplored industrial applications.
ZnCo2O4 nanowire arrays on nickel foam were synthesized through a hydrothermal and subsequent annealing process for high-performance supercapacitor electrodes.
Acyl
radical triggered difunctionalizations of aryl olefins have
been realized using oxime ester as the acyl precursor for the first
time. Irradiation of fac-Ir(ppy)3 and
oxime ester by visible light caused scission into three components,
which recombined with olefins to yield significant β-carbonyl
imides showing good functional group tolerance and high atom economy.
Control experiments as well as spectroscopic and electrochemical studies
revealed the efficient intermolecular reorganization of oxime ester
into styrene with the aid of solvent exchange.
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