Research on two-dimensional (2D) materials has been explosively increasing in last seventeen years in varying subjects including condensed matter physics, electronic engineering, materials science, and chemistry since the mechanical exfoliation of graphene in 2004. Starting from graphene, 2D materials now have become a big family with numerous members and diverse categories. The unique structural features and physicochemical properties of 2D materials make them one class of the most appealing candidates for a wide range of potential applications.In particular, we have seen some major breakthroughs made in the field of 2D materials in last five years not only in developing novel synthetic methods and exploring new structures/properties but also in identifying innovative applications and pushing forward commercialisation. In this review, we provide a critical summary on the recent progress made in the field of 2D materials with a particular focus on last five years. After a brief background 物理化学学报 Acta Phys. -Chim. Sin. 2021, 37 (12), 2108017 (3 of 151) introduction, we first discuss the major synthetic methods for 2D materials, including the mechanical exfoliation, liquid exfoliation, vapor phase deposition, and wet-chemical synthesis as well as phase engineering of 2D materials belonging to the field of phase engineering of nanomaterials (PEN). We then introduce the superconducting/optical/magnetic properties and chirality of 2D materials along with newly emerging magic angle 2D superlattices. Following that, the promising applications of 2D materials in electronics, optoelectronics, catalysis, energy storage, solar cells, biomedicine, sensors, environments, etc. are described sequentially. Thereafter, we present the theoretic calculations and simulations of 2D materials. Finally, after concluding the current progress, we provide some personal discussions on the existing challenges and future outlooks in this rapidly developing field.

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Personal moisture management fabrics that facilitate sweat transport away from the skin are highly desirable for wearer’s comfort and performance. Here, we demonstrate a “skin-like” directional liquid transport fabric, which enables continuous one-way liquid flow through spatially distributed channels acting like “sweating glands” yet repels external liquid contaminants. The water transmission rate can be 15 times greater than that of best commercial breathable fabrics. This exceptional property is achieved by creating gradient wettability channels across a predominantly superhydrophobic substrate. The flow directionality is explained by the Gibbs pinning criterion. The permeability, mechanical property, and abrasion resistance (up to 10,000 cycles) of the fabric were not affected by the treatment. In addition to functional clothing, this concept can be extended for developing materials for oil-water separation, wound dressing, geotechnical engineering, flexible microfluidics, and fuel cell membranes.

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Heterogeneous cellular network (Hetnets), where various classes of low power base stations (BS) are underlaid in a macro-cellular network, is a promising technique for future green communications. These new types of BSs can achieve substantial improvement in spectrum-efficiency and energy-efficiency via cell splitting. However, mobile stations perceive different channel gains to different base stations. Therefore, it is important to associate a mobile station with the right BS so as to achieve a good communication quality. Oftentimes, the already-challenging BS association problem is further complicated by the need of transmission power control, which is an essential component to manage co-channel interference in many wireless communications systems. Despite its importance, the joint BS association and power control (JBAPC) problem has remained largely unsolved, mainly due to its non-convex and combinatorial nature that makes the global optimal solution difficult to obtain. This paper aims to circumvent this difficulty by proposing a novel algorithm based on Benders' Decomposition to solve the non-convex JBAPC problem efficiently and optimally. In particular, we endeavor to maximize the system revenue and meanwhile associate every served mobile station with the right BS with the minimum total transmission power. We first propose a single-stage formulation that captures the two objectives simultaneously. The problem is then transformed in a way that can be efficiently solved using the proposed joint BS Association and poweR coNtrol algorithm (referred to as BARN) that is derived from classical Benders' Decomposition. Finally, we derive a closed-form analytical formula to characterize the effect of the termination criterion of the algorithm on the gap between the obtained solution and the optimal one. For practical implementation, we further propose an Accelerated BARN (A-BARN) algorithm that can significantly reduce the computational time. By carefully choosing the termination criterion, both BARN and A-BARN are guaranteed to converge to the global optimal solution.