Reactions of CuI and 5-(3-pyridyl)tetrazole in CH3CN and n-BuOH/NH3·H2O gave, respectively, the dual-channel emissive coordination polymers, 1 as a conglomerate of enantiomers and 2 as a meso condensate, which exhibits thermochromic luminescence.
A tripodal linker with six pendant methylthio (-SCH3) groups was crystallized with Zn(II) ions to provide metal-organic framework (MOF) crystals, namely NOTT-6SMe-Zn, bearing three kinds of cage-like pores. NOTT-6SMe-Zn gives...
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