Plants adapt to high altitudes by adjusting the characteristics of their above and underground organs. Identifying the species-specific plant traits changed in response to altitude is essential for understanding ecophysiological processes at the ecosystem level. Multiple studies analyzed the effects of altitude on above and underground organ traits in different species. Yet, little is known about those responses in the alpine Fritillaria przewalskii Maxim. (Liliaceae). F. przewalskii is a perennial medicinal plant with meager annual growth and vanishing wild populations. We analyzed leaf and bulb functional traits, and their allometric relationships in F. przewalskii plants grown at three altitudes: 3000, 2700, and 2400 m. Leaf thickness, leaf biomass, leaf biomass allocation, and the aboveground:underground ratio increased significantly with increasing altitude. Conversely, bulb allocation decreased at higher altitudes. The altitude influenced the allometric growth trajectories of specific leaf and bulb traits: higher altitudes led to thicker and broader leaves and changed the shape of the bulbs from more circular, which is ideal (at 2700 m), to more elongated (at 3000 m). Those variations had remarkable ecological significance. Hence, bulb biomass is the largest at 2700 m of altitude for which their vertical and longitudinal ratio is unaffected. which is economically favorable. Our findings show that F. przewalskii has a notable potential of growth and morphological plasticity along the altitude gradient and that 2700 m might be ideal for developing its artificial cultivation.
In this study, lychee-like TiO2@Fe2O3 microspheres with a core-shell structure have been prepared by coating Fe2O3 on the surface of TiO2 mesoporous microspheres using the homogeneous precipitation method. The structural and micromorphological characterization of TiO2@Fe2O3 microspheres has been carried out using XRD, FE-SEM, and Raman, and the results show that hematite Fe2O3 particles (7.05% of the total mass) are uniformly coated on the surface of anatase TiO2 microspheres, and the specific surface area of this material is 14.72 m2 g−1. The electrochemical performance test results show that after 200 cycles at 0.2 C current density, the specific capacity of TiO2@Fe2O3 anode material increases by 219.3% compared with anatase TiO2, reaching 591.5 mAh g−1; after 500 cycles at 2 C current density, the discharge specific capacity of TiO2@Fe2O3 reaches 273.1 mAh g−1, and its discharge specific capacity, cycle stability, and multiplicity performance are superior to those of commercial graphite. In comparison with anatase TiO2 and hematite Fe2O3, TiO2@Fe2O3 has higher conductivity and lithium-ion diffusion rate, thereby enhancing its rate performance. The electron density of states (DOS) of TiO2@Fe2O3 shows its metallic nature by DFT calculations, revealing the essential reason for the high electronic conductivity of TiO2@Fe2O3. This study presents a novel strategy for identifying suitable anode materials for commercial lithium-ion batteries.
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