Ambient atmospheric aerosol particles comprised of various inorganic and organic substances ubiquitously undergo phase transition, such as efflorescence, amorphization, and especially liquid-liquid phase separation (LLPS). Resultant changes of physicochemical properties in aerosols then deeply affect the climate system. However, finely detecting these processes occurring in single aerosol particles, especially under the acidic condition of real atmospheric environment, remains a challenge. In this work, we investigated the pH-dependent phase separation in single levitated microdroplets using a self-developed laser tweezers Raman spectroscopy (LTRS) system. The dynamic process of LLPS in laser-trapped droplets over the course of humidity cycles was detected with the time-resolved cavity-enhanced Raman spectra. These measurements provide the first comprehensive account of the pH-dependent LLPS in single levitated aerosol microdroplets and bring possible implications on phase separation in actual atmospheric particles.
Viscosity is a fundamental physicochemical property of aerosol particles that influences chemical evolution, mass transfer rates, and particle formation etc., and also changes with ambient relative humidity (RH). However, the...
We propose a novel CNN model named RamanNet for rapid and accurate identification of bacteria at the species-level based on Raman spectra. Compared to previous CNN methods, the RamanNet reached comparable results on the Bacteria-ID Raman spectral dataset.
The hygroscopicity and volatility of airborne particles depict the thermodynamic process of the gas-particle partition of semivolatile organic components, which then have substantial impacts on the atmospheric chemistry and lifetime...
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