Perovskite solar cells (PSCs) has skyrocketed in the past decade to an unprecedented level due to their outstanding photoelectric properties and facile processability. However, the utilization of expensive hole transport materials (HTMs) and the inevitable instability instigated by the deliquescent dopants represent major concerns hindering further commercialization. Here, a series of low-cost, conjugated polymers are designed and applied as dopantfree HTMs in PSCs, featuring tuned energy levels, good temperature and humidity resistivity, and excellent photoelectric properties. Further studies highlight the critical and multifaceted roles of the polymers with respect to facilitating charge separation, passivating the surface trap sites of perovskite materials, and guaranteeing long-term stability of the devices. A stabilized power conversion efficiency (PCE) of 20.3% and remarkably enhanced device longevity are achieved using the dopant-free polymer P3 with a low concentration of 5 mg/mL, qualifying the device as one of the best PSC systems constructed on the basis of dopant-free HTMs so far. In addition, the flexible PSCs based on P3 also exhibit a PCE of 16.2%. This work demonstrates a promising route toward commercially viable, stable, and efficient PSCs.
Conjugated polymers
are regarded as promising candidates for dopant-free
hole-transport materials (HTMs) in efficient and stable perovskite
solar cells (PSCs). Thus far, the vast majority of polymeric HTMs
feature structurally complicated benzo[1,2-b:4,5-b’]dithiophene (BDT) analogs and electron-withdrawing
heterocycles, forming a strong donor–acceptor (D–A)
structure. Herein, a new class of phenanthrocarbazole (PC)-based polymeric HTMs (PC1, PC2, and PC3) has been synthesized by inserting a PC unit
into a polymeric thiophene or selenophene chain with the aim of enhancing
the π–π stacking of adjacent polymer chains and
also to efficiently interact with the perovskite surface through the
broad and planar conjugated backbone of the PC. Suitable
energy levels, excellent thermostability, and humidity resistivity
together with remarkable photoelectric properties are obtained via
meticulously tuning the conformation and elemental composition of
the polymers. As a result, PSCs containing PC3 as dopant-free
HTM show a stabilized power conversion efficiency (PCE) of 20.8% and
significantly enhanced longevity, rendering one of the best types
of PSCs based on dopant-free HTMs. Subsequent experimental and theoretical
studies reveal that the planar conformation of the polymers contributes
to an ordered and face-on stacking of the polymer chains. Furthermore,
introduction of the “Lewis soft” selenium atom can passivate
surface trap sites of perovskite films by Pb–Se interaction
and facilitate the interfacial charge separation significantly. This
work reveals the guiding principles for rational design of dopant-free
polymeric HTMs and also inspires rational exploration of small molecular
HTMs.
Adequate hole mobility is the prerequisite for dopant-free polymeric hole-transport materials (HTMs). Constraining the configurational variation of polymer chains to affordarigid and planar backbone can reduce unfavorable reorganization energy and improve hole mobility.H erein, an oncovalent conformational locking via S-O secondary interaction is exploited in ap henanthrocarbazole (PC)b ased polymeric HTM, PC6,t of ix the molecular geometry and significantly reduce reorganization energy.S ystematic studies on structurally explicit repeats to targeted polymers reveals that the broad and planar backbone of PC remarkably enhances pp stacking of adjacent polymers,f acilitating intermolecular charge transfer greatly.T he inserted "Lewis soft" oxygen atoms passivate the trap sites efficiently at the perovskite/HTM interface and further suppress interfacial recombination. Consequently,aPSC employing PC6 as adopant-free HTM offers an excellent power conversion efficiency of 22.2 %a nd significantly improved longevity,r endering it as one of the best PSCs based on dopant-free HTMs.
The dioxygen formation mechanism of biological water oxidation in nature has long been the focus of argument; many diverse mechanistic hypotheses have been proposed. Based on a recent breakthrough in the resolution of the electronic and structural properties of the oxygen-evolving complex in the S state, our density functional theory (DFT) calculations reveal that the open-cubane oxo-oxyl coupling mechanism, whose substrates preferably originate from W2 and O5 in the S state, emerges as the best candidate for O-O bond formation in the S state. This is justified by the overwhelming energetic superiority of this mechanism over alternative mechanisms in both the isomeric open and closed-cubane forms of the MnCaO cluster; spin-dependent reactivity rooted in variable magnetic couplings was found to play an essential role. Importantly, this oxygen evolution mechanism is supported by the recent discovery of femtosecond X-ray free electron lasers (XFEL), and the origin of the observed structural changes from the S to S state has been analyzed. In this view, we corroborate the proposed water binding mechanism during S-S transition and correlate the theoretical models with experimental findings from aspects of substrate selectivity according to water exchange kinetics. This theoretical consequence for native metalloenzymes may serve as a significant guide for improving the design and synthesis of biomimetic materials in the field of photocatalytic water splitting.
Single crystals of Spiro(TFSI)2 were grown and structurally determined. The optical and electronic properties were investigated and compared with neutral Spiro-OMeTAD.
A new class of polymeric hole‐transport materials (HTMs) are explored by inserting a two‐dimensionally conjugated fluoro‐substituted pyrene into thiophene and selenophene polymeric chains. The broad conjugated plane of pyrene and “Lewis soft” selenium atoms not only enhance the π–π stacking of HTM molecules greatly but also render a strong interaction with the perovskite surface, leading to an efficient charge transport/transfer in both the HTM layer and the perovskite/HTM interface. Note that fluorine substitution adjacent to pyrene boosts the stacking of HTMs towards a more favorable face‐on orientation, further facilitating the efficient charge transport. As a result, perovskite solar cells (PSCs) employing PE10 as dopant‐free HTM afford an excellent efficiency of 22.3 % and the dramatically enhanced device longevity, qualifying it among the best PSCs based on dopant‐free HTMs.
Carbazole is a promising core for the molecular design of hole‐transport materials (HTMs) for solid‐state mesoscopic solar cells (ssMSCs), such as solid‐state dye‐sensitized solar cells (ssDSSCs) and perovskite solar cells (PSCs) due to its low cost and excellent optoelectronic properties of its derivatives. Although carbazole‐based HTMs are intensely investigated in ssMSCs and promising device performance is demonstrated, the fundamental understanding of the impact of linking topology on the properties of carbazole‐based HTMs is lacking. Herein, the effect of the linking topology on the optical and electronic properties of a series of carbazole‐based HTMs with 2,7‐substitution and 3,6‐substitution is systematically investigated. The results demonstrate that the 2,7‐substituted carbazole‐based HTMs display higher hole mobility and conductivity among this series of analogous molecules, thereby exhibiting better device performance. In addition, the conductivity of the HTMs is improved after light treatment, which explains the commonly observed light‐soaking phenomenon of ssMSCs in general. All these carbazole‐based HTMs are successfully applied in ssMSCs and one of the HTMs X50‐based devices yield a promising efficiency of 6.8% and 19.2% in ssDSSCs and PSCs, respectively. This study provides guidance for the molecular design of effective carbazole‐based HTMs for high‐performance ssMSCs and related electronic devices.
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