The mechanism and synthetic perspectives of an indirect cathodic amination of unsaturated and aromatic substrates are considered. The influence of experimental conditions on the state and reactivity of the aminating reagent in solution is studied. The key role of the electrolyte acidity and redox properties of the reagents and intermediates in the obtained isomeric composition and the yield of the amination products is demonstrated.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.