Poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) (PEDOT/PSS) was synthesized by oxidative polymerization and pH dependence of structure and electrical conductivity of the cast films were investigated by means of UV-vis-NIR, XRD, AFM analyses, and four-point technique. It was found that the neutralization of PEDOT/PSS with NaOH decreased the absorption of bipolarons representing the PEDOT in the highly doped state and disrupted the π-π stacking of the PEDOT crystalline structure, which lowered the electrical conductivity by six orders of magnitude with increasing the pH from 1.7 to 13.
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Poly(3,4ethylenedioxythiophene) doped with poly(4styrenesulfonate) (PEDOT/PSS) with various PSS composition ratios (α) was synthesized by oxidative polymerization and particle size distribution and zeta potential of the resulting colloidal gel particles were investigated by means of a dynamic light scattering technique. It was found that mean volume diameter of the PEDOT/PSS colloidal gel particles were 400600 nm at α = 1~6, which drastically decreased to ~10 nm at α = 8~15. On the other hand, zeta potential was about 80 mV regardless of the composition ratio. The electrical conductivity of the PEDOT/PSS cast film measured by a fourpoint method attained as high as 263 S/cm at α = 3.
Atomically thin two-dimensional (2D) mechanical resonators should realize highly sensitive force sensors and high performance nano-electro-mechanical systems due to their excellent electrical and mechanical properties. However, practical applications require stability of the resonance frequencies against temperature. Here, we demonstrate the manipulation of the thermal expansion coefficients (TECs) by creating a van der Waals heterojunction using graphene and MoS2, which have opposite signs of TECs. Our method greatly suppresses the apparent TEC of the 2D heterojunction to 1/3 of the monolayer graphene without the detraction of the tunability of the resonance frequency by electrostatic attraction. 1
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