The theoretical extinction coefficients of gold nanoparticles (AuNPs) have been mainly verified by the analytical solving of the Maxwell equation for an ideal sphere, which was firstly founded by Mie (generally referred to as Mie theory). However, in principle, it has not been directly feasible with experimental verification especially for relatively large AuNPs (i.e., >40 nm), as conventionally proposed synthetic methods have inevitably resulted in a polygonal shaped, non-ideal Au nanosphere. Here, mono-crystalline, ultra-smooth, and highly spherical AuNPs of 40-100 nm were prepared by the procedure reported in our recent work (ACS Nano, 2013, 7, 11064). The extinction coefficients of the ideally spherical AuNPs of 40-100 nm were empirically extracted using the Beer-Lambert law, and were then compared with the theoretical limits obtained by the analytical and numerical methods. The obtained extinction coefficients of the ideally spherical AuNPs herein agree much more closely with the theoretical limits, compared with those of the faceted or polygonal shaped AuNPs. In addition, in order to further elucidate the importance of being spherical, we systematically compared our ideally spherical AuNPs with the polygonal counterparts; effectively addressing the role of the surface morphology on the spectral responses in both theoretical and experimental manners.
Atomic force microscope (AFM)-enabled manipulation of individual metallic nanoparticles (NPs) has proven useful for assembling diverse structural motifs of metamolecules. However, for the reliable verifications of their electric/magnetic behaviors and translations into practical applications (e.g., metasurfaces), currently available assembly of polygonal shaped metallic NPs with size and shape distributions should be further advanced. Here, we discover conditions for AFM-enabled, deterministic assembly of highly uniform, super-spherical gold NPs (AuNPs) into the metamolecules, which can show the designed electric/magnetic resonance behaviors in a highly reliable fashion. The use of super-spherical AuNPs together with the controlled adhesive properties of an AFM tip allows us to linearly and continuously push AuNPs toward the pre-programed directions and positions with minimized slipping away effect. Thus, a versatile and fast (as little as few minutes per each metamolecule) assembly of metamolecules with unprecedented structural fidelity becomes possible via AFM-enabled manipulation; enabling a high precision engineering of electromagnetic properties with metamolecules.
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