No abstract

Aimed to enhance the high‐temperature service performance of C/SiC composites in high‐speed aircraft thermal protection system, in this article, pitch‐based carbon fibers were used to construct high thermal conductive channels to improve the heat transfer capability of C/SiC composites. The results revealed that the as‐prepared composites equipped with 4.7 times higher thermal conductivity than that of conventional C/SiC composites. The oxyacetylene flame ablation test confirmed that the constructed high thermal conductive channels, which quickly conducted the heat flow from the ablation center area to other areas is the main reason of as‐prepared composites exhibiting a very impressive ablation resistance property. Briefly, the ablation temperature of the as‐prepared composite surfaces considerably dropped by about 300°C compared with conventional C/SiC composites, while the linear ablation rate and mass ablation rate of the composites are 1.27 μm/s and 0.61 mg/s respectively, which is superior to many recent reports, demonstrating that this article provides a simple but highly effective measure to improve the ablation resistance property of C/SiC composites.

A series of photosensitive zirconia ceramic slurry with adjustable viscosity and cured depth have been presented for the construction of high‐quality zirconia ceramic fabricated by digital light processing 3D printing. The rheological and curing behavior of the slurry can be flexibly optimized by tuning the reactive diluent concentration and category, since the change of dominant position of diluent on viscosity and the different curing mode. Monofunctional reactive diluent (HEA, hydroxyethyl acrylate) exhibits an enhanced dilution effect compared with that of bifunctional reactive diluent (HDDA, 1,6‐hexamethylene diacrylate) due to the lower molecular mass of monofunctional diluent. As a result, the viscosity reaches lower than 2000 mPa·s when the concentration of both HEA and HDDA exceeds 50 wt.%. At the same time, the non‐Newtonian properties of the slurry are also changed, which facilitates the printing process. However, excessive addition of diluent may generate more defects in ceramic green body. Consequently, the cured depth of zirconia slurry can reach 55 and 50 µm, respectively, at the curing time of 3 s while introducing the HEA or HDDA with the concentration below 70 wt.%, and the modified feedstock is promising for high‐quality and low‐defect zirconia ceramic components printing for biomedical applications.