The controlled synthesis of highly crystalline MoS2 atomic layers remains a challenge for the practical applications of this emerging material. Here, we developed an approach for synthesizing MoS2 flakes in rhomboid shape with controlled number of layers by the layer-by-layer sulfurization of MoO2 microcrystals. The obtained MoS2 flakes showed high crystallinity with crystal domain size of ~10 μm, significantly larger than the grain size of MoS2 grown by other methods. As a result of the high crystallinity, the performance of back-gated field effect transistors (FETs) made on these MoS2 flakes was comparable to that of FETs based on mechanically exfoliated flakes. This simple approach opens up a new avenue for controlled synthesis of MoS2 atomic layers and will make this highly crystalline material easily accessible for fundamental aspects and various applications.
Solid-state lithium metal batteries (SSLMBs) are promising
energy
storage devices by employing lithium metal anodes and solid-state
electrolytes (SSEs) to offer high energy density and high safety.
However, their efficiency is limited by Li metal/SSE interface barriers,
including insufficient contact area and chemical/electrochemical incompatibility.
Herein, a strategy to effectively improve the adhesiveness of Li metal
to garnet-type SSE is proposed by adding only a few two-dimensional
boron nitride nanosheets (BNNS) (5 wt %) into Li metal by triggering
the transition from point contact to complete adhesion between Li
metal and ceramic SSE. The interface between the Li-BNNS composite
anode and the garnet exhibits a low interfacial resistance of 9 Ω
cm2, which is significantly lower than that of bare Li/garnet
interface (560 Ω cm2). Furthermore, the enhanced
contact and the additional BNNS in the interface act synergistically
to offer a high critical current density of 1.5 mA/cm2 and
a stable electrochemical plating/striping over 380 h. Moreover, the
full cell paired with the Li-BNNS composite anode and the LiFePO4 cathode shows stable cycling performance at room temperature.
Our results introduce an appealing composite strategy with two-dimensional
materials to overcome the interface challenges, which provide more
opportunities for the development of SSLMBs.
Solid electrolytes
potentially provide safety, Li dendrites blocking,
and electrochemical stability in Li-metal batteries. Large efforts
have been devoted to disperse ceramic nanoparticles in a poly(ethylene
oxide) (PEO) matrix to improve the ions transport. However, it is
challengeable to create efficient framework for ions transport with
nanoparticles. Here we report for the first time garnet nanosheets
to provide interconnected Li-ions transport pathway in a PEO matrix.
The garnet nanosheet fillers would not only facilitate ions transport
but also enhance ionic conductivity in comparison with their nanoparticle
counterparts. A composite solid polymer electrolyte containing 15
wt % garnet nanosheets exhibits a practically useful conductivity
of 3.6 × 10–4 S cm–1 at room
temperature. Besides, the composite electrolyte can robustly isolate
Li dendrites in a symmetric lithium metal-composite electrolyte battery
during reversible Li dissolution/deposition at a relatively low temperature
of 40 °C. The symmetric cell with composite electrolyte shows
flat voltage and low interfacial resistance over a galvanostatic
cycling of 200 h at a current density of 0.1 mA cm–2. A solid-state Li/LiFePO4 battery with the composite
polymer electrolyte exhibits a capacity of 98.1 mAh g–1 and a capacity retention of 97.5% after 30 cycles at a temperature
of 40 °C. This finding provides a strategy to explore superionic
conductors.
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