In this study, modified zeolites were prepared through the modification of raw zeolites, using hydrochloric acid (HCl) and cetyl trimethyl ammonium bromide (CTAB), whose properties were then characterized by a Zeta Potential Meter and an X-ray diffractometer. Also, the adsorption mechanisms were investigated in depth. The experimental results indicated that, in terms of the adsorption capacity of Rhodamine B in water, the modified zeolites were more favorable than the raw zeolites. As the dosage of adsorbent increased, the removal percentage of Rhodamine B in the water increased, while the unit adsorption capacity decreased. The pH value of the solution, and reaction temperature imposed little effects on the adsorption of the Rhodamine B. In accordance with the adsorption thermodynamic results, Langmuir and Freundlich isothermal adsorption models were able to accurately describe the adsorption of Rhodamine B in water by the modified zeolites. The fitting results had a higher correlation when using a Freundlich isothermal model. At 303 K, the static saturated adsorption capacity was 4.41 mg/g. The kinetic results demonstrated that the adsorption of Rhodamine B in water using modified zeolites fit well with the pseudo-second-order kinetic model.
In this study, a small pulsed current electrocoagulation device was used to treat high concentration dyeing wastewater from a specific dyeing mill, and the effects of the electrode materials, reaction time, voltage, pH value, and aeration on the results of the treatment were examined. The results showed that under the following operational conditions: electrode materials were iron electrodes, time period was 15 min, voltage was 120 V, and initial pH was approximately 6, the removal rates of the COD, ammonia nitrogen, and color were 79.45%, 23.89%, and 87.50%, respectively. On this basis, a pulsed current electrocoagulation device, with a handling capacity of 0.5 m 3 /h, was used to conduct a pilot plant test for a period of one month. The results showed that the effluent quality (COD 1217.4 mg/L and NH 4 + -N 358.2 mg/L on average) of the high-concentration dyeing wastewater, whose COD and NH 4 + -N concentrations were 5328 mg/L, 595 mg/L, respectively after the treatment of a pulsed current electrocoagulation reactor, was superior to the effluent quality (COD 1400 mg/L and NH 4 + -N 450 mg/L) of the mill's actual pre-treatment system (flocculation-anaerobic treatment-acidification), and fully reached the influent requirements of the subsequent aerobic treatment. The results of this study showed that pulsed current electrocoagulation reactors may be effectively used for the pre-treatment of high concentration dyeing wastewater due to the observed advantages, such as good treatment effects, small investment, and economical space occupation.
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