Ground tire rubber (GTR) with crosslinked structure has hardly any plasticity and processability, which makes its property very poor. Thermal-mechanical shearing devulcanization method can effectively destroy the crosslinked structure and restore GTR a certain extent of plasticity and processability. This article investigated the characteristic and reprocessing performance of reclaimed rubber prepared through thermal-mechanical shearing devulcanization. The relationship between the devulcanization level (indicated by gel fraction and crosslink density) and the mechanical property was analyzed by sufficient experiments. Fourier transform infrared spectroscopy and elemental analyzer studies revealed the chemical structure of GTR changed and many complex reactions occurred after devulcanization. The gel permeation chromatography indicated the specific changes of molecular weight and molecular weight distribution in devulcanization process. The differential scanning calorimetry revealed various vulcanized abilities and vulcanized structures of reclaimed rubber. The scanning electron microscope further confirmed the recovery of plasticity after devulcanization and the distinct vulcanized structures between revulcanizates. The determination of devulcanization level and mechanical properties verified that mechanical properties especially tensile strength reached to the optimum value only at an appropriate devulcanization level.
In this work, poly(ethylene terephthalate)
(PET) chain-extending
products with different molecular weights were prepared by reactive
extrusion using isocyanate trimer (C-HK) as the trifunctional chain
extender. The effect of the chain extender C-HK on the intrinsic viscosity,
melt flow property, crystallization behavior, crystallization morphology,
and mechanical property of PET was investigated. The results showed
that when the content of the chain extender was increased from 0.6
to 1.4 wt%, the viscosity average molecular weight of PET was effectively
increased from 2.36 × 10
4
to 5.46 × 10
4
g·mol
–1
. After the chain extending, the crystallinity
and the time of semicrystallization of PET were significantly decreased.
After the isothermal crystallization at 220 °C for 5 min, the
spherulites formed by pure PET became larger. With the increase in
molecular weight of PET after chain extension, its spherulite size
was significantly decreased without changing the crystalline structure.
The chain-extended PET also exhibited more excellent bending-resistant
and impact-resistant properties. While the tensile strength of PET
after chain extension was slightly decreased, the bending strength
was increased by a maximum value of 56.8%, and the impact strength
was increased by a maximum value of five times.
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