We report high-fidelity laser-beam-induced quantum logic gates on magnetic-field-insensitive qubits comprised of hyperfine states in 9 Be + ions with a memory coherence time of more than 1 s. We demonstrate single-qubit gates with error per gate of 3.8(1) × 10 −5 . By creating a Bell state with a deterministic two-qubit gate, we deduce a gate error of 8(4) × 10 −4 . We characterize the errors in our implementation and discuss methods to further reduce imperfections towards values that are compatible with fault-tolerant processing at realistic overhead.Quantum computers can solve certain problems that are thought to be intractable on conventional computers. An important general goal is to realize universal quantum information processing (QIP), which could be used for algorithms having a quantum advantage over processing with conventional bits as well as to simulate other quantum systems of interest [1][2][3]. For large problems, it is generally agreed that individual logic gate errors must be reduced below a certain threshold, often taken to be around 10 −4 [4][5][6], to achieve fault tolerance without excessive overhead in the number of physical qubits required to implement a logical qubit. This level has been achieved in some experiments for all elementary operations including state preparation and readout, with the exception of two-qubit gates, emphasizing the importance of improving multi-qubit gate fidelities. [7,8]. As various ions differ in mass, electronic, and hyperfine structure, they each have technical advantages and disadvantages. For example, 9 Be + is the lightest ion currently considered for QIP, and as such, has several potential advantages. The relatively light mass yields deeper traps and higher motional frequencies for given applied potentials, and facilitates fast ion transport [9,10]. Light mass also yields stronger laser-induced effective spin-spin coupling (inversely proportional to the mass), which can yield less spontaneous emission error for a given laser intensity [11]. However, a disadvantage of 9 Be + ion qubits compared to some heavier ions such as 40 Ca + and 43 Ca + [12, 13] has been the difficulty of producing and controlling the ultraviolet (313 nm) light required to drive 9 Be + stimulated-Raman transitions. In the work reported here, we use an ion trap array designed for scalable QIP [14] and take advantage of recent technological developments with lasers and optical fibers that improve beam quality and pointing stability. We also implement active control of laser pulse intensities to re- duce errors. We demonstrate laser-induced single-qubit computational gate errors of 3.8(1) × 10 −5 and realize a deterministic two-qubit gate to ideally produce the Bell state |Φ + = 1 √ 2 (|↑↑ + |↓↓ ). By characterizing the effects of known error sources with numerical simulations and calibration measurements, we deduce an entangling gate infidelity or error of = 8(4) × 10 −4 , where = 1 -F, and F is the fidelity. Along with Ref.[13]; these appear to be the highest two-qubit gate fidelitie...

Precision laser spectroscopy 1 of cold and trapped molecular ions is a powerful tool for fundamental physics, including the determination of fundamental constants 2 , the laboratory test for their possible variation 3,4 , and the search for a possible electric dipole moment of the electron 5 . While the complexity of molecular structure facilitates these applications, the absence of cycling transitions poses a challenge for direct laser cooling 6 , quantum state control [7][8][9][10][11] , and detection. Previously employed state detection techniques based on photodissociation 12 or chemical reactions 13 are destructive and therefore inefficient, restricting the achievable resolution in laser spectroscopy. Here we experimentally demonstrate nondestructive state detection of a single trapped molecular ion through its strong Coulomb coupling to a well-controlled co-trapped atomic ion. An algorithm based on a state-dependent optical dipole force 14 (ODF) changes the internal state of the atom conditioned on the internal state of the molecule. We show that individual quantum states in the molecular ion can be distinguished by their coupling strength to the ODF and observe black-body radiationinduced quantum jumps between rotational states of a single molecular ion. Using the detuning dependence of the state detection signal, we implement a variant of quantum logic spectroscopy 15,16 of a molecular resonance. The state detection technique we demonstrate is applicable to a wide range of molecular ions, enabling further applications in state-controlled quantum chemistry 17 and spectroscopic investigations of molecules serving as probes for interstellar clouds 18,19 .One of the salient features of trapped ion systems is that the universal Coulomb interaction allows strong coupling of diverse quantum objects, such as different species of atomic ions or atomic and molecular ions. Being able to perform quantum logic operations e.g. in the form of gates 14,20,21 between the quantum objects has proven a powerful tool for quantum information processing and quantum simulations in such systems. It also allows combining the advantages of different atomic species. Quantum logic spectroscopy is one such application in which the high degree of control achieved over selected atomic ions is extended to species over which such control is lacking 15,16 . Here, we demonstrate for the first time quantum logic operations between a single molecular ion and a co-trapped atomic ion, making a wide range of molecular ions accessible to this highlydeveloped toolbox. The presented technique allows the investigation of single molecules in a well isolated system avoiding disturbance from the environment, which is the limiting factor in other implementations of single molecule spectroscopy such as surface enhanced Raman spectroscopy (SERS) 22 Quantum logic operations between atoms are based on state dependent forces often induced by laser fields. The same approach is applicable to molecular ions. The coupling is now distributed over many ro-vibrat...

Precision control over hybrid physical systems at the quantum level is important for the realization of many quantum-based technologies. In the field of quantum information processing (QIP) and quantum networking, various proposals discuss the possibility of hybrid architectures where specific tasks are delegated to the most suitable subsystem. For example, in quantum networks, it may be advantageous to transfer information from a subsystem that has good memory properties to another subsystem that is more efficient at transporting information between nodes in the network. For trapped ions, a hybrid system formed of different species introduces extra degrees of freedom that can be exploited to expand and refine the control of the system. Ions of different elements have previously been used in QIP experiments for sympathetic cooling, creation of entanglement through dissipation, and quantum non-demolition measurement of one species with another. Here we demonstrate an entangling quantum gate between ions of different elements which can serve as an important building block of QIP, quantum networking, precision spectroscopy, metrology, and quantum simulation. A geometric phase gate between a (9)Be(+) ion and a (25)Mg(+) ion is realized through an effective spin-spin interaction generated by state-dependent forces induced with laser beams. Combined with single-qubit gates and same-species entangling gates, this mixed-element entangling gate provides a complete set of gates over such a hybrid system for universal QIP. Using a sequence of such gates, we demonstrate a CNOT (controlled-NOT) gate and a SWAP gate. We further demonstrate the robustness of these gates against thermal excitation and show improved detection in quantum logic spectroscopy. We also observe a strong violation of a CHSH (Clauser-Horne-Shimony-Holt)-type Bell inequality on entangled states composed of different ion species.

Along with the development of industry and the improvement of people’s living standards, peoples’ demand on resources has greatly increased, causing energy crises and environmental pollution. In recent years, photocatalytic technology has shown great potential as a low-cost, environmentally-friendly, and sustainable technology, and it has become a hot research topic. However, current photocatalytic technology cannot meet industrial requirements. The biggest challenge in the industrialization of photocatalyst technology is the development of an ideal photocatalyst, which should possess four features, including a high photocatalytic efficiency, a large specific surface area, a full utilization of sunlight, and recyclability. In this review, starting from the photocatalytic reaction mechanism and the preparation of the photocatalyst, we review the classification of current photocatalysts and the methods for improving photocatalytic performance; we also further discuss the potential industrial usage of photocatalytic technology. This review also aims to provide basic and comprehensive information on the industrialization of photocatalysis technology.

We demonstrate an efficient high-precision optical spectroscopy technique for single trapped ions with nonclosed transitions. In a double-shelving technique, the absorption of a single photon is first amplified to several phonons of a normal motional mode shared with a cotrapped cooling ion of a different species, before being further amplified to thousands of fluorescence photons emitted by the cooling ion using the standard electron shelving technique. We employ this extension of the photon recoil spectroscopy technique to perform the first high precision absolute frequency measurement of the 2 D 3=2 → 2 P 1=2 transition in calcium, resulting in a transition frequency of f ¼ 346 000 234 867ð96Þ kHz. Furthermore, we determine the isotope shift of this transition and the 2 S 1=2 → 2 P 1=2 transition for 42 Ca þ , 44 Ca þ , and 48 Ca þ ions relative to 40 Ca þ with an accuracy below 100 kHz. Improved field and mass shift constants of these transitions as well as changes in mean square nuclear charge radii are extracted from this high resolution data.