Structural analysis was performed on a purple laser diode composed of In0.20Ga0.80N (3 nm)/ In0.05Ga0.95N (6 nm) multiple quantum wells, by employing transmission electron microscopy and energy-dispersive x-ray microanalysis, both of which are assessed from the cross-sectional direction. It was found that the contrast of light and shade in the well layers corresponds to the difference in In composition. The main radiative recombination was attributed to excitons localized at deep traps which probably originate from the In-rich region in the wells acting as quantum dots. Photopumped lasing was observed at the high energy side of the main spontaneous emission bands.
We demonstrate the fabrication of blue, green, and amber InGaN/GaN light-emitting diodes (LEDs) on semipolar {11-22} bulk GaN substrates. The {11-22}GaN substrates used in this study are produced by cutting out from a c-oriented GaN bulk crystal grown by hydride vapor epitaxy. The LEDs have a dimension of 320 ×320 µm2 and are packed in an epoxide resin. The output power and external quantum efficiency (EQE) at a driving current of 20 mA are 1.76 mW and 3.0%, respectively, for the blue LED, 1.91 mW and 4.1% for the green LED, and 0.54 mW and 1.3% for the amber LED. The maximum output powers obtained with a maximum current of 200 mA are 19.0 mW (blue), 13.4 mW (green), and 1.9 mW (amber), while the maximum EQEs are 4.0% at 140 mA (blue), 4.9% at 0.2 mA (green), and 1.6% at 1 mA (amber). It is confirmed that the emission light is polarized along the [1-100] direction, reflecting the low crystal symmetry of the {11-22} plane.
Solid state UV emitters have many advantages over conventional UV sources. The (Al,In,Ga)N material system is best suited to produce LEDs and laser diodes from 400 nm down to 210 nm—due to its large and tuneable direct band gap, n- and p-doping capability up to the largest bandgap material AlN and a growth and fabrication technology compatible with the current visible InGaN-based LED production. However AlGaN based UV-emitters still suffer from numerous challenges compared to their visible counterparts that become most obvious by consideration of their light output power, operation voltage and long term stability. Most of these challenges are related to the large bandgap of the materials. However, the development since the first realization of UV electroluminescence in the 1970s shows that an improvement in understanding and technology allows the performance of UV emitters to be pushed far beyond the current state. One example is the very recent realization of edge emitting laser diodes emitting in the UVC at 271.8 nm and in the UVB spectral range at 298 nm. This roadmap summarizes the current state of the art for the most important aspects of UV emitters, their challenges and provides an outlook for future developments.
We observed a 32-fold increase in the spontaneous emission rate of InGaN/GaN quantum well ͑QW͒ at 440 nm by employing surface plasmons ͑SPs͒ probed by time-resolved photoluminescence spectroscopy. We explore this remarkable enhancement of the emission rates and intensities resulting from the efficient energy transfer from electron-hole pair recombination in the QW to electron vibrations of SPs at the metal-coated surface of the semiconductor heterostructure. This QW-SP coupling is expected to lead to a new class of super bright and high-speed light-emitting diodes ͑LEDs͒ that offer realistic alternatives to conventional fluorescent tubes. © 2005 American Institute of Physics. ͓DOI: 10.1063/1.2010602͔Currently, InGaN-GaN quantum well ͑QW͒ based lightemitting diodes ͑LEDs͒ have been developed and expected to eventually replace more traditional fluorescent tubes as illumination sources. 1,2 However, the emission efficacy of commercial white LEDs is still substantially lower than that of fluorescent tubes. 3 Recently, we have reported a method for enhancing the light emission efficiency from InGaN QWs by controlling the energy transfer between QW emitters and surface plasmons ͑SPs͒. 4 The idea of SP enhanced light emission was previously described 5-15 and efficient SPenhanced visible light emission has been demonstrated. 4 Moreover, the enhancement of an emission rate is also very important for the development of communication technology and optical computing. However, spontaneous emission rates of InGaN-GaN QWs are usually reduced by the carrier localization effect 16,17 and the quantum confinement Stark effect, 18,19 and very difficult to enhance. There are only a few reports on the enhancement of the emission rates by reducing the piezo-electric field 20 and making photonic crystal structure. 21 We believe that our developed SP coupling technique has the potential to enhance the spontaneous emission rate dramatically. 4 Since the density of states of SP mode is much larger, the QW-SP coupling rate should be very fast, and this new path of a recombination can increase the spontaneous emission rate. However, clear evidence for fast rate of QW-SP coupling has not so far been reported on the SP enhanced emission. We investigate the direct observation of SP coupled spontaneous emission rate by using the timeresolved photoluminescence ͑PL͒ measurements here. Moreover, we consider the mechanisms and dynamics of energy transfer and light extraction. This study should also be very useful for further optimization of the QW-SP coupling condition and for designing even more efficient device structures.InGaN-GaN QW wafers were grown on 0001 oriented sapphire substrates by metal-organic chemical vapor deposition ͑MOCVD͒. The grown structures consist of a GaN ͑4 m͒ buffer layer, an InGaN SQW ͑3 nm͒ followed by a GaN cap layer ͑10 nm͒. A 50 nm thick silver layer was then evaporated on top of the wafer surface. To perform timeresolved PL measurements, the frequency doubled output from a mode-locked Ti: Al 2 O 3 laser was used to...
We investigated correlations between nanoscopic optical and structural properties in violet-emitting, blueemitting, and green-emitting In x Ga 1−x N / GaN quantum wells ͑QWs͒ by means of scanning near-field optical microscopy ͑SNOM͒ and atomic force microscopy. Only in the blue-emitting QW, threading dislocations were not major nonradiative recombination centers ͑NRCs͒. SNOM data indicated that NRCs in the blue-emitting QW are surrounded by energy levels higher than those for radiative recombination. Such potential distributions realize "antilocalization" of carriers to NRCs, which is the cause of high emission quantum efficiencies in blue emitters.
In x Ga 1 − x N multiple quantum wells (QWs) with [0001], ⟨112¯2⟩, and ⟨112¯0⟩ orientations have been fabricated by means of the regrowth technique on patterned GaN template with striped geometry, normal planes of which are (0001) and {112¯0}, on sapphire substrates. It was found that photoluminescence intensity of the {112¯2} QW is the strongest among the three QWs, and the internal quantum efficiency of the {112¯2} QW was estimated to be as large as about 40% at room temperature. The radiative recombination lifetime of the {112¯2} QW was about 0.38ns at low temperature, which was 3.8 times shorter than that of conventional [0001]-oriented InxGa1−xN QWs emitting at a similar wavelength of about 400nm. These findings strongly suggest the achievement of stronger oscillator strength owing to the suppression of piezoelectric fields.
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