The main purpose of this study was to analyze the effect of coal mining on the springs in the Yushenfu mining area of China. The results of two springs and hydrological surveys conducted in 1994 and 2015 were compared to study the occurrence and evolution of springs before and after large-scale mining. The mechanism of spring evolution and ecological effects of domain evolution were analyzed by combined groundwater monitoring and evaluation of coal mining intensity. The results show that the maximum amount of single water inflow of spring with sand infiltration recharge was more than 10 L/s, the total amount of single water inflow of spring with mixed infiltration recharge was the highest, and the ecological effect of spring with loess infiltration recharge was the most significant. In the study area, 2580 springs (group) were distributed with a total flow of 4998.9428 L/s before 1994 and 376 residual springs (group) were present with a total flow of 996.392 L/s in 2015. Large-scale mining decreased the regional groundwater level, thus decreasing the amount of spring water. The high intensity of mining decreased the number of springs (group) and area of water and wetland in the study area. This directly affected the watershed ecology; the ecological degradation was significant.
Groundwater of Luohe Formation is the main water source for industrial and agricultural and residential use in Binchang mining area, which is one of the key elements to water conservation coal mining. However, few studies are available to document the enrichment characteristics and influence of underground coal mining on groundwater for the Luohe Formation. This study evaluates the changes of groundwater levels and spring flow caused by mining activities to explore the influence mechanism of coal mining on groundwater by comparatively analysing existing mining data and survey data combined with a series of mapping methods. The results show that the aquifer of Luohe Formation are gradually thinning south-eastwards, disappeared at the mining boundary. In the vertical direction, the lithological structure is distinct, due to alternative sedimentation of meandering river facies and braided river facies. According to the yielding property, the aquifer is divided into three sections, namely, strong water-rich section, medium water-rich section, and weak water-rich section, which are located in northwest and central part, southwest, and the rest part of the mining area, respectively. Mining of Tingnan Coal Mine since 2004 has caused a 3.16 to 194.87 meters drop in groundwater level of Luohe Formation. Until 2015, 70.10% of the mining area undergoes a groundwater level drop larger than 10.00 meters. Another influence of underground mining is that the total flow from 34 springs in 8 southern coal mines of the area has decreased by 286.48 L/s with a rate of decrease at 46.95% from 2007 to 2017. The areas that groundwater level falls or spring flow declines are manly located in the mine gob areas. Results also indicate that the ratio of the height of water conducted fracture zone to the mining height in Binchang mining area is between 16.85 and 27.92. This may increase ground water flow in vertical direction, causing a water level in the aquifer system to drop and ultimately decreasing the flow from the springs. The research results will provide data and theoretical support for the protection of groundwater resources and water conservation coal mining of Luohe Formation in Binchang mining area.
Plasma-activated water (PAW) has been utilised in various application fields, and a deep understanding on the plasma chemistry is the foundation of application-orientated optimisation. In this paper, a global model is built to study the chemical properties of PAW produced by a dielectric barrier discharge that is powered by nanosecond voltage pulses. The applied voltage is firstly repeated with 10 kHz frequency for 100 s, and then shut down for 200 s afterglow, providing a long-term evolution regarding the production and consumption of some typical reactive oxygen/nitrogen species (RONS) in PAW. The calculated results agree principally with experimental measurements from literature. During the pulsed discharge, the water gradually acidises, and the long-lived species accumulate; while in the afterglow, most of the aqueous RONS decay rapidly, except for O 3aq , NO − 3aq , H 2 O 2aq and N 2 O aq , which might be the main sources to sustain long-term effects. Furthermore, the effects of applied voltage and gap distance on RONS are investigated. Correlation analyses from Pearson correlation coefficient indicate that gaseous RONS are more sensitive to the gap distance, while the aqueous ones are more sensitive to the voltage amplitude, suggesting the possibility to independently regulating the gaseous and aqueous chemistry.
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