Designing high-efficiency and stable metal selenides for visible-light-induced photocatalytic H2 production has been challenging. Here, a novel class of Se-rich MnCdSe solid solutions with tunable band structure is fabricated through...
Metal selenide semiconductors in photocatalysis are limited, owing to their low activity and poor stability. Herein, a facile one‐pot solution approach is developed to prepare particulate Zn
x
Cd1−x
Se solid solutions with tunable energy band structures. X‐ray diffractometer (XRD) patterns demonstrate that the crystal structure of the samples are not changed. The analysis of UV–vis and the photoluminescence spectra exhibits that the bandgap of Zn
x
Cd1−x
Se photocatalysts utilizing oleylamine as an organic template can be accurately controlled, which gradually becomes wider from 1.60 to 2.70 eV with increasing Zn/Cd molar ratio. Under visible‐light irradiation, the optimal Zn0.5Cd0.5Se without any cocatalyst exhibits a superior photocatalytic H2 generation rate (438.3 μmol h−1 g−1), exceeding that of pristine CdSe and ZnSe by more than 12 and 17 times, an apparent quantum yield of 1.7% at 420 nm and excellent stability. The results are on account of the balance between the bandgap width and the conduction band (CB) potential of Zn0.5Cd0.5Se, implying the excitation of more photogenerated electrons and faster charge carrier separation efficiency, which could be substantiated by the transient photocurrent response and electrochemical impedance spectroscopy. Therefore, this work provides a straightforward strategy to synthesize metal selenide for diverse photocatalytic applications.
In this work, we used a template-free method to synthesize zinc sulfide (ZnS) materials. The photocatalytic performances of the samples were evaluated, and the physical natures of the ZnS nanocrystals were determined by photoluminescence (PL). Interestingly, the temperature-dependent PL variations of the samples were very different in connection with the synthesis condition. Combined with a series of catalytic experiments, it suggested that the intrinsic self-absorption of PL and photon recycling play key roles in photocatalysis. This work gives a new idea for understanding the photocatalysis and presents a new strategy to design ZnS related photocatalysts for further applications.
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