A several of basic ionic liquids
(ILs) were synthesized as green
solvents and catalysts for the preparation of 1,8-naphthyridyl derivatives
via the Friedlander reaction. [Bmmim][Im] exhibited remarkable catalytic
activity to achieve the synthetic targets, and the reaction conditions
were optimized. The model product 2,3-diphenyl-1,8-naphthyridine (1,8-Nap),
with carboxyethylthiosuccinic acid (CETSA) to form an IL corrosion
inhibitor ([1,8-Nap][CETSA]), and its corrosion inhibition performance
for Q235 steel in 1 M HCl were researched by weight loss measurements,
and the results showed that the inhibition efficiency was 96.95% when
the concentration of [1,8-Nap][CETSA] was 1 mM at 35 °C. The
electrochemical test verified that [1,8-Nap][CETSA] acted as a mixed-type
inhibitor but mainly exhibited cathodic behavior. The inhibitor adsorbed
on the metal surface was further proved by surface topography analysis.
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