Aqueous rechargeable zinc ion batteries have attracted expanded attention for large-scale energy storage owing to their cost-effectiveness, safety and high volumetric energy density. However, aqueous rechargeable zinc ion batteries still...
Lithium-ion batteries (LIBs) represent the most promising choice for meeting the ever-growing demand of society for various electric applications, such as electric transportation, portable electronics, and grid storage. Nickel-rich layered oxides have largely replaced LiCoO2 in commercial batteries because of their low cost, high energy density, and good reliability. Traditional nickel-based oxide particles, usually called polycrystal materials, are composed of microsized primary particles. However, polycrystal particles tend to suffer from pulverization and severe side reactions along grain boundaries during cycling. These phenomena accelerate cell degradation. Single-crystal materials, which exhibit robust mechanical strength and a high surface area, have great potential to address the challenges that hinder their polycrystal counterparts. A comprehensive understanding of the growing body of research related to single-crystal materials is imperative to improve the performance of cathodes in LIBs. This review highlights origins, recent developments, challenges, and opportunities for single-crystal layered oxide cathodes. The synthesis science behind single-crystal materials and comparative studies between single-crystal and polycrystal materials are discussed in detail. Industrial techniques and facilities are also reviewed in combination with our group’s experiences in single-crystal research. Future development should focus on facile production with strong control of the particle size and distribution, structural defects, and impurities to fully reap the benefits of single-crystal materials.
Graphical abstract
Reduced graphene oxide (rGO) sheet decorated Na3V2(PO4)3 (NVP) microspheres were successfully synthesized by spray-drying method. The NVP microspheres were embedded by rGO sheets, and the surface of the particles were coated by rGO sheets and amorphous carbon. Thus, the carbon conductive network consisted of rGO sheets and amorphous carbon generated in the cathode material. NVP microspheres decorated with different content of rGO (about 0, 4, 8, and 12 wt%) were investigated in this study. The electrochemical performance of NVP exhibited a significant enhancement after rGO introduction. The electrode containing about 8 wt% rGO (NVP/G8) showed the best rate and cycle performance. NVP/G8 electrode exhibited the discharge capacity of 64.0 mAh g−1 at 70°C, and achieved high capacity retention of 95.5% after cycling at 10°C for 100 cycles. The polarization of the electrode was inhibited by the introduction of rGO sheets. Meanwhile, compared with the pristine NVP electrode, NVP/G8 electrode exhibited small resistance and high diffusion coefficient of sodium ions.
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