The solid-electrolyte interphase (SEI) layer is pivotal for the stable and rechargeable batteries especially under high rate. However, the mechanism of Li+ transport through the SEI has not been clearly...
Lithium‐sulfur (Li‐S) batteries are one of the most promising next‐generation energy‐storage systems. Nevertheless, the sluggish sulfur redox and shuttle effect in Li‐S batteries are the major obstacles to their commercial application. Previous investigations on adsorption for LiPSs have made great progress but cannot restrain the shuttle effect. Catalysts can enhance the reaction kinetics, and then alleviate the shuttle effect. The synergistic relationship between adsorption and catalysis has become the hotspot for research into suppressing the shuttle effect and improving battery performance. Herein, the adsorption‐catalysis synergy in Li‐S batteries is reviewed, the adsorption‐catalysis designs are divided into four categories: adsorption‐catalysis for LiPSs aggregation, polythionate or thiosulfate generation, and sulfur radical formation, as well as other adsorption‐catalysis. Then advanced strategies, future perspectives, and challenges are proposed to aim at long‐life and high‐efficiency Li‐S batteries.
Electrocatalytic water splitting is one of the most promising sustainable energy conversion technologies, but is limited by the sluggish electrochemical reactions. Inorganic nanomaterials have been widely used as efficient catalysts for promoting the electrochemical kinetics. Several approaches to optimize the activities of these nanocatalysts have been developed. The electronic structures of the catalysts play a pivotal role in governing the activity and thus have been identified as an essential descriptor. However, the underlying working mechanisms related to the refined electronic structures remain elusive. To establish the structure–electronic‐behavior–activity relationship, a comprehensive overview of the developed strategies to regulate the electronic structures is presented, emphasizing the surface modification, strain, phase transition, and heterostructure. Current challenges to the fundamental understanding of electron behaviors in the nanocatalysts are fully discussed.
despite all these promises, three intrinsic drawbacks need to be resolved before fulfilling the promise of the market potential.First, the most stable but electronically insulating S 8 (≈10 −14 S cm −2 ) with cyclic configuration is used as the starting material in Li-S cathode, significantly limiting the full utilization of the active materials to reach the theoretical capacity. Therefore, it is the first priority to design the cathode that ensures the maximum usage of the starting materials, which sets the upper limit of the capacity performance. Second, the muti-step reduction process releases highly soluble lithium polysulfides (LiPSs) intermediates (Li 2 S x , where x = 4-8) into the organic electrolyte. [6] Unlike the batteries based on ion-insertion mechanism, [7,8] Li-S battery possesses unique and complex electrochemical/chemical processes during operation. During galvanostatic discharge process, two distinct plateaus can be verified at about 2.4 and 2.1 V in the voltage profile, corresponding to the reduction of sulfur into long-chain polysulfides and subsequent reaction from short-chain polysulfides to Li 2 S, respectively. [9] Further investigations about the reaction mechanism of Li-S battery based on experimental and theoretical studies reveal that the existence of various intermediates during electrochemical processes, indicating much more complex battery chemistry compared to the simple stepwise reaction model. [10,11] As a result, the soluble intermediates can diffuse through the polymeric separator to the anode surface, causing the loss of active materials and degradation of anode. Third, the density difference between the starting material (sulfur, 2.07 g cm −3 ) and discharge product (Li 2 S, 1.66 g cm −3 ) causes significant volumetric change during continuous cycling, damaging the integrity of the cathode structure and leading to serious capacity fading. [12] Besides above problems concerning the cathode side of the Li-S battery, other issues arose on the anode side, such as the unstable solid-electrolyte interphase (SEI), surface passivation, and uncontrolled lithium dendrite growth. [13][14][15] Stemmed from the basic problems mentioned above from the very beginning of the designed Li-S battery systems, various derivative problems were gradually unraveled during persistent efforts for improving the battery performance to approach the ultimate goal for commercialization. In the past decade, fundamental studies about Li-S battery were carried in laboratories all over the world, and it gradually put the puzzle together while brought promising performance improvement. [11,[16][17][18][19][20] However, to date, most of the lab-scale progresses have been based on batteries with sulfur loading lower than 2 mg cm −2 , Lithium-sulfur (Li-S) batteries, due to the high theoretical energy density, are regarded as one of the most promising candidates for breaking the limitations of energy-storage system based on Li-ion batteries. Tremendous efforts have been made to meet the challenge of high-performan...
The oxygen evolution reaction (OER) has been explored extensively for reliable hydrogen supply to boost the energy conversion efficiency. The superior OER performance of newly developed non‐noble metal electrocatalysts has concealed the identification of the real active species of the catalysts. Now, the critical active phase in nickel‐based materials (represented by NiNPS) was directly identified by observing the dynamic surface reconstruction during the harsh OER process via combining in situ Raman tracking and ex situ microscopy and spectroscopy analyses. The irreversible phase transformation from NiNPS to α‐Ni(OH)2 and reversible phase transition between α‐Ni(OH)2 and γ‐NiOOH prior to OER demonstrate γ‐NiOOH as the key active species for OER. The hybrid catalyst exhibits 48‐fold enhanced catalytic current at 300 mV and remarkably reduced Tafel slope to 46 mV dec−1, indicating the greatly accelerated catalytic kinetics after surface evolution.
Fast lithium ion transport with a high current density is critical for thick sulfur cathodes, stemming mainly from the difficulties in creating effective lithium ion pathways in high sulfur content electrodes. To develop a high-rate cathode for lithium-sulfur (Li-S) batteries, extenuation of the lithium ion diffusion barrier in thick electrodes is potentially straightforward. Here, a phyllosilicate material with a large interlamellar distance is demonstrated in high-rate cathodes as high sulfur loading. The interlayer space (≈1.396 nm) incorporated into a low lithium ion diffusion barrier (0.155 eV) significantly facilitates lithium ion diffusion within the entire sulfur cathode, and gives rise to remarkable nearly sulfur loading-independent cell performances. When combined with 80% sulfur contents, the electrodes achieve a high capacity of 865 mAh g at 1 mA cm and a retention of 345 mAh g at a high discharging/charging rate of 15 mA cm , with a sulfur loading up to 4 mg. This strategy represents a major advance in high-rate Li-S batteries via the construction of fast ions transfer paths toward real-life applications, and contributes to the research community for the fundamental mechanism study of loading-independent electrode systems.
The potential roles of CD8 ϩ T-cell-induced chemokines in the expansion of immune responses were examined using DNA immunogen constructs as model antigens. We coimmunized cDNA expression cassettes encoding the ␣ -chemokines IL-8 and SDF-1 ␣ and the  -chemokines MIP-1 ␣ , RANTES, and MCP-1 along with DNA immunogens and analyzed the resulting antigen-specific immune responses.
Immunization with nucleic acids has been shown to induce both antigen-specific cellular and humoral immune responses in vivo. We hypothesize that immunization with DNA could be enhanced by directing specific immune responses induced by the vaccine based on the differential correlates of protection known for a particular pathogen. Recently we and others reported that specific immune responses generated by DNA vaccine could be modulated by co-delivery of gene expression cassettes encoding for IL-12, granulocyte-macrophage colony-stimulating factor and the co-stimulatory molecule CD86. To further engineer the immune response in vivo, we investigated the induction and regulation of immune responses following the co-delivery of pro-inflammatory cytokine (IL-1 alpha, TNF-alpha, and TNF-beta), Th1 cytokine (IL-2, IL-12, IL-15, and IL-18), and Th2 cytokine (IL-4, IL-5 and IL-10) genes. We observed enhancement of antigen-specific humoral response with the co-delivery of Th2 cytokine genes IL-4, IL-5, and IL-10 as well as those of IL-2 and IL-18. A dramatic increase in antigen-specific T helper cell proliferation was seen with IL-2 and TNF-alpha gene co-injections. In addition, we observed a significant enhancement of the cytotoxic response with the co-administration of TNF-alpha and IL-15 genes with HIV-1 DNA immunogens. These increases in CTL response were both MHC class I restricted and CD8+ T cell dependent. Together with earlier reports on the utility of co-immunizing using immunologically important molecules together with DNA immunogens, we demonstrate the potential of this strategy as an important tool for the development of more rationally designed vaccines.
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