Innovative technologies are highly pursued for the detection and avoidance of counterfeiting in modern information society. Herein, we report the construction of photo-responsive supramolecular polymers toward fluorescent anti-counterfeit applications, by taking advantage of multicycle anthracene‒endoperoxide switching properties. Due to σ-metalation effect, photo-oxygenation of anthracene to endoperoxide is proceeded under the mild visible light irradiation conditions, while the backward conversion occurs spontaneously at room temperature. Supramolecular polymers are formed with cooperative nucleation‒elongation mechanism, which facilitate fluorescence resonance energy transfer process via two-component co-assembly strategy. Fluorescence resonance energy transfer efficiency is delicately regulated by either light-triggered anthracene‒endoperoxide conversion or vapor-induced monomer–polymer transition, leading to high-contrast fluorescent changes among three different states. On this basis, dual-mode anti-counterfeiting patterns have been successfully fabricated via inkjet printing techniques. Hence, cooperative supramolecular polymerization of photo-fluorochromic molecules represents an efficient approach toward high-performance anti-counterfeit materials with enhanced security reliability, fast response, and ease of operation.
Ordered porous solid-state architectures constructed via non-covalent supramolecular self-assembly have attracted increasing interest due to their unique advantages and potential applications. Porous metal-coordination organic frameworks (MOFs) are generated by the assembly of metal coordination centers and organic linkers. Compared to MOFs, porous hydrogen-bonded organic frameworks (HOFs) are readily purified and recovered via simple recrystallization. However, due to lacking of sufficiently ability to orientate self-aggregation of building motifs in predictable manners, rational design and preparation of porous HOFs are still challenging. Herein, we summarize recent developments about porous HOFs and attempt to gain deeper insights into the design strategies of basic building motifs.
We report preliminary results on the analysis of the three-body Υ( 10860) → B Bπ, Υ(10860) → [B B * + c.c.]π and Υ(10860) → B * B * π decays including an observation of the Υ(10860) → Z ± b (10610)π ∓ → [B B * + c.c.] ± π ∓ and Υ(10860) → Z ± b (10650)π ∓ → [B * B * ] ± π ∓ decays as intermediate channels. We measure branching fractions of the three-body decays to be B(Υ(10860) → [B B * + c.c.] ± π ∓ ) = (28.3 ± 2.9 ± 4.6) × 10 −3 and B(Υ(10860) → [B * B * ] ± π ∓ ) = (14.1 ± 1.9 ± 2.4) × 10 −3 and set 90% C.L. upper limit B(Υ(10860) → [B B] ± π ∓ ) < 4.0 × 10 −3 . We also report results on the amplitude analysis of the three-body Υ(10860) → Υ(nS)π + π − , n = 1, 2, 3 decays and the analysis of the internal structure of the three-body Υ(10860) → h b (mP )π + π − , m = 1, 2 decays. The results are based on a 121.4 fb −1 data sample collected with the Belle detector at a center-of-mass energy near the Υ(10860).
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