Practical, efficient synthesis of metal oxide nanocrystals with good crystallinity and high specific surface area by a modified polymer-network gel method is demonstrated, taking ZnO nanocrystals as an example. A novel stepwise heat treatment yields significant improvement in crystal quality. Such nanophase materials can effectively degrade common organic dyes under solar radiation and can perform very well in photo-assisted detection of NO2 gas. Other typical metal oxide nanocrystals with good crystallinity and high specific surface area were also synthesized successfully under similar conditions. This work provides a general strategy for the synthesis of metal oxide nanocrystals, balancing the crystallinity and specific surface area.
Single‐atom metal‐insulator‐semiconductor (SMIS) heterojunctions based on Sn‐doped Fe2O3 nanorods (SF NRs) were designed by combining atomic deposition of an Al2O3 overlayer with chemical grafting of a RuOx hole‐collector for efficient CO2‐to‐syngas conversion. The RuOx‐Al2O3‐SF photoanode with a 3.0 nm thick Al2O3 overlayer gave a >5‐fold‐enhanced IPCE value of 52.0 % under 370 nm light irradiation at 1.2 V vs. Ag/AgCl, compared to the bare SF NRs. The dielectric field mediated the charge dynamics at the Al2O3/SF NRs interface. Accumulation of long‐lived holes on the surface of the SF NRs photoabsorber aids fast tunneling transfer of hot holes to single‐atom RuOx species, accelerating the O2‐evolving reaction kinetics. The maximal CO‐evolution rate of 265.3 mmol g−1 h−1 was achieved by integration of double SIMS‐3 photoanodes with a single‐atom Ni‐doped graphene CO2‐reduction‐catalyst cathode; an overall quantum efficiency of 5.7 % was recorded under 450 nm light irradiation.
This paper presents a rapid traversability assessment approach based on an extended 2.5D grid-based representaion of the rough terrain. Stereo vision system is used to perceive the environment surrounding robot. Conventional 2D, 3D and other 2.5D grid maps determine the traversability indices of the grids directly from the sensor feedback, while our approach attempts to address the indices of terrain from multiple grids instead. By analyzing the properties of multiple grids that the robot is to traverse, passable grids are distinguished, which also takes the robot's size into account. Fuzzy logic framework is applied to extract traversabiltiy indices from the terrain characteristics. A soccer robot equipped with a stereo vision system is adopted for experiments. The results show that our map is capable of speeding the process of traversability assessment and providing an autonomous mobile robot with a appropriate representation of 3D uneven terrain profile.
Erbium-doped lithium niobate on insulator (Er:LNOI) is a promising platform for photonic integrated circuits as it adds gain to the LNOI system and enables on-chip lasers and amplifiers. A challenge for Er:LNOI laser is to increase its output power while maintaining single-frequency and single (-transverse)-mode operation. In this work, we demonstrate that single-frequency and single-mode operation can be achieved even in a single multi-mode Er:LNOI microring by introducing mode-dependent loss and gain competition. In a single microring with a free spectral range of 192 GHz, we have achieved single-mode lasing with an output power of 2.1 μW, a side-mode suppression of 35.5 dB, and a linewidth of 1.27 MHz.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.