The
catalyst layer’s high durability is essential in commercializing
polymer electrolyte membrane fuel cells (PEMFCs), particularly for
vehicle applications, because their frequent on/off operation can
induce carbon corrosion, which affects surface properties and morphological
characteristics of the carbon and results in aggregation and detachment
of Pt nanoparticles on the carbon surface. Herein, to address the
carbon corrosion problem while delivering a high-performance PEMFC,
polydimethylsiloxane (PDMS) with high gas permeability, chemical stability,
and hydrophobicity was employed to protect the catalyst layer from
carbon corrosion and improve the mass transport. Because the catalyst
slurry using alcohol-based solvents showed low compatibility with
nonpolar solvents of the PDMS solution, a parallel two-nozzle system
with separated solution reservoirs was developed by modifying a conventional
three-dimensional printing machine. To determine the optimal PDMS
amount in the cathode catalyst layer, PDMS solution concentration
was varied by quantitatively controlling the PDMS amount coated on
the electrode layer. Finally, the PEMFC with the PDMS-modified cathode
of 0.1 mgPDMS cm–2 loading showed enhanced
durability due to increased electrochemical surface and maximum power
density by 37.2 and 21.7%, respectively, after the accelerated stress
test. Furthermore, an improvement in the initial performance from
enhanced water management was observed compared to those of PEMFCs
with a conventional electrode.
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