Liquid metal is being regarded as a promising material for soft electronics owing to its distinct combination of high electrical conductivity comparable to that of metals and exceptional deformability derived from its liquid state. However, the applicability of liquid metal is still limited due to the difficulty in simultaneously achieving its mechanical stability and initial conductivity. Furthermore, reliable and rapid patterning of stable liquid metal directly on various soft substrates at high-resolution remains a formidable challenge. In this work, meniscus-guided printing of ink containing polyelectrolyte-attached liquid metal microgranular-particle in an aqueous solvent to generate semi-solid-state liquid metal is presented. Liquid metal microgranular-particle printed in the evaporative regime is mechanically stable, initially conductive, and patternable down to 50 μm on various substrates. Demonstrations of the ultrastretchable (~500% strain) electrical circuit, customized e-skin, and zero-waste ECG sensor validate the simplicity, versatility, and reliability of this manufacturing strategy, enabling broad utility in the development of advanced soft electronics.

A common design concept of the piezoelectric force sensor, which is to assemble a bump structure from a flat or fine columnar piezoelectric structure or to use a specific type of electrode, is quite limited. In this paper, we propose a new design of cylindrical piezoelectric sensors that can detect multidirectional forces. The proposed sensor consists of four row and four column sensors. The design of the sensor was investigated by the finite element method. The response of the sensor to various force directions was observed, and it was demonstrated that the direction of the force applied to the sensor could be derived from the signals of one row sensor and three column sensors. As a result, this sensor proved to be able to detect forces in the area of 225° about the central axis of the sensor. In addition, a cylindrical sensor was fabricated to verify the proposed sensor and a series of experiments were performed. The simulation and experimental results were compared, and the actual sensor response tended to be similar to the simulation.

Liquid metal (LM) is being regarded as the most feasible material for soft electronics owing to its distinct combination of high conductivity comparable to that of metals and exceptional deformability derived from its liquid state. However, the applicability of LM is still limited due to the difficulty of achieving its mechanical stability and intrinsic conductivity. Furthermore, reliable and rapid patterning of stable LM directly on various soft substrates at high-resolution remains a formidable challenge. In this work, meniscus-guided printing of ink containing polyelectrolyte-attached LM microgranular-particle (PaLMP) in an aqueous solvent to generate semi-solid-state LM is presented. PaLMP printed in the evaporative regime is mechanically stable, intrinsically conductive, and patternable down to 50 µm on various substrates. Demonstrations of the ultrastretchable (~500% strain) electrical circuit, customized e-skin, and zero-waste ECG sensor validate the simplicity, versatility, and reliability of this manufacturing strategy, enabling broad utility in the development of advanced soft electronics.