With the development of science and technology, photocatalytic technology is of great interest. Nanosized photocatalysts are easy to agglomerate in an aqueous solution, which is unfavorable for recycling. Therefore, hydrogel-based photocatalytic composites were born. Compared with other photocatalytic carriers, hydrogels have a three-dimensional network structure, high water absorption, and a controllable shape. Meanwhile, the high permeability of these composites is an effective way to promote photocatalysis technology by inhibiting nanoparticle photo corrosion, while significantly ensuring the catalytic activity of the photocatalysts. With the growing energy crisis and limited reserves of traditional energy sources such as oil, the attention of researchers was drawn to natural polymers. Like almost all abundant natural polymer compounds in the world, cellulose has the advantages of non-toxicity, degradability, and biocompatibility. It is used as a class of reproducible crude material for the preparation of hydrogel photocatalytic composites. The network structure and high hydroxyl active sites of cellulose-based hydrogels improve the adsorption performance of catalysts and avoid nanoparticle collisions, indirectly enhancing their photocatalytic performance. In this paper, we sum up the current research progress of cellulose-based hydrogels. After briefly discussing the properties and preparation methods of cellulose and its descendant hydrogels, we explore the effects of hydrogels on photocatalytic properties. Next, the cellulose-based hydrogel photocatalytic composites are classified according to the type of catalyst, and the research progress in different fields is reviewed. Finally, the challenges they will face are summarized, and the development trends are prospected.
Materials with excellent biocompatibility and targeting can be widely used in the biomedical field. Hydrogels are an excellent biomedical material, which are similar to living tissue and cannot affect the metabolic process of living organisms. Moreover, the three-dimensional network structure of hydrogel is conducive to the storage and slow release of drugs. Compared to the traditional hydrogel preparation technologies, ionizing radiation technology has high efficiency, is green, and has environmental protection. This technology can easily adjust mechanical properties, swelling, and so on. This review provides a classification of hydrogels and different preparation methods and highlights the advantages of ionizing radiation technology in smart hydrogels used for biomedical applications.
Environmental pollution, especially water pollution, is becoming increasingly serious. Organic dyes are one type of the harmful pollutants that pollute groundwater and destroy ecosystems. In this work, a series of graphitic carbon nitride (g-C3N4)/ZnO photocatalysts were facilely synthesized through a grinding method using ZnO nanoparticles and g-C3N4 as the starting materials. According to the results, the photocatalytic performance of 10 wt.% CN-200/Z-500 (CN-200, which g-C3N4 was 200 kGy, referred to the irradiation metering. Z-500, which ZnO was 500 °C, referred to the calcination temperature) with the CN-200 exposed to electron beam radiation was better than those of either Z-500 or CN-200 alone. This material displayed a 98.9% degradation rate of MB (20 mg/L) in 120 min. The improvement of the photocatalytic performance of the 10 wt.% CN-200/Z-500 composite material was caused by the improvement of the separation efficiency of photoinduced electron–hole pairs, which was, in turn, due to the formation of heterojunctions between CN-200 and Z-500 interfaces. Thus, this study proposes the application of electron-beam irradiation technology for the modification of photocatalytic materials and the improvement of photocatalytic performance.
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