CsPbX3 (X = Cl, Br, I) perovskite nanocrystals (NCs),
including zero-dimensional (0D) quantum dots (QDs), one-dimensional
(1D) nanorods (NRs), and two-dimensional (2D) nanoplatelets (NPLs),
have shown promising performances in light-emitting diode (LED) and
lasing applications. However, Auger recombination, one of the key
processes that limit their performance, remains poorly understood
in CsPbX3 2D NPLs and 1D NRs. We show that the biexciton
Auger lifetimes of CsPbBr3 NPLs (NRs) scale linearly with
the NPL lateral area (NR length) and deviates from the “universal
volume scale law” that has been observed for QDs. These results
are consistent with a model in which the Auger recombination rate
for 1D NRs and 2D NPLs is a product of binary collision frequency
in the nonquantum confined dimension and Auger probability per collision.
Comparisons of Auger recombination in CsPbBr3 NCs of different
dimensionalities and similar band gaps suggest that Auger probability
increases in NCs with a higher number of confined dimensions. Compared
to CdSe and PbSe NCs with the same dimensionalities and similar sizes,
Auger recombination rates in 0D–2D CsPbBr3 NCs are
over 10-fold faster. Fast Auger recombination in CsPbBr3 NCs shows their potentials for Auger-assisted up-conversion and
single photon source, while suppressing Auger recombination may further
enhance their performances in LED and lasing applications.
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