Conjugated polymers offer unique combination of easily tailored mechanical, electrical and optical properties that makes them perfect materials for the preparation of various devices such as light-emitting diodes, photovoltaic cells or field-effect transistors. However, the design and fabrication of such devices in a controlled and reproducible way are possible only if the behavior and the properties of individual polymer chains are well understood. One major problem in this respect is that aggregation often occurs even in dilute solutions and prevents the single polymer chain studies. To address this issue, in this work we employed fluorescence correlation spectroscopy (FCS) to study the behavior of a model conjugated polymer, poly(2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene) (MEH-PPV) in several commonly used solvents. The very high sensitivity of FCS allowed measurements in ultradilute solutions and thus unambiguous determination of the hydrodynamic radius of single polymer chains. The solvent quality for MEH-PPV was then quantitatively evaluated from the measured logarithmic scaling of the single chain hydrodynamic radius versus the polymer molecular weight. Scaling exponents of 0.40, 0.41, and 0.43 were found in toluene, chloroform and 1,2-dichlorobenzene, respectively. These values are well below the θ-condition, emphasizing poor solvent quality for MEH-PPV, despite the fact that all studied solvents are commonly regarded as “good” solvents. In addition, by investigating the aggregation behavior of MEH-PPV at higher polymer concentrations, we found a clear relation between aggregates size and solvatochromism that indicates more extended chain conformation in larger aggregates..
The heat island phenomenon in major cities is partly due to the excessive use of concrete and brick, which causes many problems regarding thermal comfort and energy expenditure. The thermal behaviour of the envelope wall material depends on its density, heat capacity, and thermal conductivity, and its effect on the heat island intensity (HII) is reported in this paper. Experiments and simulations were carried out on the four most popular building materials: brick, aerated concrete, wood with glass-wool insulation, and glass fibre-reinforced concrete with glass-wool insulation, with each material having a dimension of 1 m × 1 m. Experiments to analyse the thermal behaviour of the wall materials were performed by exposing each material to heat radiation from 2 × 1000 W halogen lamps for 4 h, followed by 4 h of cooling. The HII simulations were carried out in a simple urban kampong in a tropical area using Energy2D software. Heat flow analyses confirmed the thermal behaviour of the four walls, which can be categorised into two types: heat storage of block wall (BW) type and heat flow inhibition of insulated sandwich wall (ISW) type. The BW type showed 0.32 °C higher indoor air temperature than the ISW type, while the HII simulation showed ISW to be 0.74 °C higher than BW; however, both types increase the intensity and need mitigation treatment. The results of this study are important for the technological approach for dealing with local warming to lower the energy expenditure of poor people in an urban area. Keywords Urban heat island • Thermal behaviour • Block wall type • Insulated sandwich wall • Urban kampong List of symbols ρ Density c Specific heat κ Thermal conductivity avg Average density c avg Average specific heat avg Average thermal conductivity T so Outer surface temperature T si Inner surface temperature T m1 Temperature of the core wall at a depth of 2.5 cm T m2 Temperature of the core wall at a depth of 7.5 cm T m3 Temperature of the core wall at a depth of 12.5 cm P so Heat flow at outer surface P m1 Heat flow at a depth of 2.5 cm P m2 Heat flow at a depth of 7.5 cm P m3 Heat flow at a depth of 12.5 cm P si Heat flow at inner surface T ao Outdoor air temperature T ai Indoor air temperature T ac Outdoor air temperature above the canopy layer
Oil spills in the marine environment are a rising concern due to their adverse impacts on living creatures and the environment. Hence, remediation methods have been used to remove the oil from the contaminated water. A sorbent material is considered the best method for oil spill absorption. However, commonly used commercial sorbents are made from nonrenewable and nonenvironmentally friendly materials. In this research, natural rubber foam (NRF) was used as a sorbent material with the addition of a filler, i.e., silica and a silica–lignin hybrid, to increase its oil sorption capacity and reusability. The silica and silica–lignin hybrid were extracted from rice husk waste by means of the precipitation method. The silica–lignin hybrid-filled NRF exhibited excellent hydrophobicity, with a water contact angle of 133°, and had more stable reusability compared to unfilled NRF and silica-filled NRF. In addition, the optimum oil absorption capacity of silica–lignin hybrid-filled NRF was 1.36 g g−1. Overall, the results showed that silica–lignin hybrid-filled NRF has the potential to be developed as a green oil absorbent material and is promising in terms of economic and environmental aspects.
Lignin isolated from black liquor waste was studied in this research to be utilized as binderless, all-lignin briquette, with a calorific value in the range of 5670–5876 kcal/kg. Isolation of lignin from black liquor was conducted using the acid precipitation method. Sulfuric acid, citric acid, and acetic acid were used to maintain the pH level, which varied from 5 to 2 for the precipitation process. The influence of these isolation conditions on the characteristic of lignin and the properties of the resulted briquette was evaluated through the Klasson method, proximate analysis, ultimate analysis, Fourier Transform Infrared (FTIR), adiabatic bomb calorimeter, density measurement, and Drop Shatter Index (DSI) testing. The finding showed that the lignin isolated using citric acid maintained to pH 3 resulted in briquette with 72% fixed carbon content, excellent 99.7% DSI, and a calorific value equivalent to coal-based briquette.
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