Dye-sensitized solar cells with power conversion efficiencies of up to 6.5% have been fabricated using a cobalt tris-bipyridyl redox mediator with the cis-diisothiocyanato-(2,2′-bipyridyl-4,4′-dicarboxylic acid)-(2,2′-bipyridyl-4,4′-dinonyl) ruthenium(II) (Z907) sensitizer. This represents a significant improvement in efficiency compared with previous reports using ruthenium sensitizers. In situ near-IR transmittance measurements in conjunction with electrochemical impedance spectroscopy have been used to explain the difference in performance between DSCs using Z907 and another benchmark sensitizer cis-diisothiocyanato-bis(2,2′-bipyridyl-4,4′-dicarboxylic acid) ruthenium(II) bis(tetrabutylammonium) (N719). It is found that the small-perturbation electron diffusion length (L n ) is significantly longer in Z907 cells compared with that in N719 cells, which can explain most of the difference in performance. It is also shown that the longer L n in Z907 cells is caused by inhibited recombination, as opposed to faster transport, and possible reasons for this are discussed. Our methodological approach is especially useful for accurately determining L n when it is shorter than the TiO2 layer thickness, where standard dynamic techniques start to become unreliable.

A functionalized [9]cycloparaphenylene ([9]CPP) bearing three evenly spaced 5,8-dimethoxynaphth-1,4-diyl units and two macrocyclic [6]CPP precursors have been synthesized. The Diels-Alder reaction between (E,E)-1,4-bis(4-bromophenyl)-1,3-butadiene and 1,4-benzoquinone followed by methylation produces cis-5,8-bis(4-bromophenyl)-5,8-dihydro-1,4-dimethoxynaphthalene as the key intermediate for the construction of the hooplike structures. The nickel-mediated homocoupling reactions followed by aromatization led to the functionalized [9]CPP.

Three-dimensional topological insulators (3D TIs) represent states of quantum matters in which surface states are protected by timereversal symmetry and an inversion occurs between bulk conduction and valence bands. However, the bulk-band inversion, which is intimately tied to the topologically nontrivial nature of 3D Tis, has rarely been investigated by experiments. Besides, 3D massive Dirac fermions with nearly linear band dispersions were seldom observed in TIs. Recently, a van der Waals crystal, ZrTe 5 , was theoretically predicted to be a TI. Here, we report an infrared transmission study of a high-mobility [∼33,000 cm 2 /(V · s)] multilayer ZrTe 5 flake at magnetic fields (B) up to 35 T. Our observation of a linear relationship between the zero-magnetic-field optical absorption and the photon energy, a bandgap of ∼10 meV and a ffiffiffi B p dependence of the Landau level (LL) transition energies at low magnetic fields demonstrates 3D massive Dirac fermions with nearly linear band dispersions in this system. More importantly, the reemergence of the intra-LL transitions at magnetic fields higher than 17 T reveals the energy cross between the two zeroth LLs, which reflects the inversion between the bulk conduction and valence bands. Our results not only provide spectroscopic evidence for the TI state in ZrTe 5 but also open up a new avenue for fundamental studies of Dirac fermions in van der Waals materials. T opologically nontrivial quantum matters, such as topological insulators (1-8), Dirac semimetals (9-19), and Weyl semimetals (20-27), have sparked enormous interest owing both to their exotic electronic properties and potential applications in spintronic devices and quantum computing. Therein, intrinsic topological insulators have insulating bulk states with odd Z 2 topological invariants and metallic surface or edge states protected by time-reversal symmetry (4-6, 28). Most of the experimental evidence to date for TIs is provided by the measurements of the spin texture of the metallic surface states. As a hallmark of the nontrivial Z 2 topology of TIs (4-6, 28), an inversion between the characteristics of the bulk conduction and valence bands occurring at an odd number of time-reversal invariant momenta has seldom been probed by experiments. An effective approach for identifying the bulk-band inversion in TIs is to follow the evolution of two zeroth Landau levels (LLs) that arise from the bulk conduction and valence bands, respectively. As shown in Fig. 1A, for TIs, due to the bulk-band inversion and Zeeman effects, the two zeroth bulk Landau levels are expected to intersect in a critical magnetic field and then separate (3, 29); and for trivial insulators, the energy difference between their two zeroth Landau levels would become larger with increasing magnetic field. Therefore, an intersection between the two zeroth bulk LLs is a significant signature of the bulk-band inversion in TIs. However, a spectroscopic study of the intersection between the two zeroth bulk LLs in 3D TIs is still missing. In addi...

Today's Internet carries an ever broadening range of application traffic with different requirements. This has stressed its original, one-class, best-effort model, and has been one of the main drivers behind the many efforts aimed at introducing QoS. Those efforts have, however, experienced only limited success because their added complexity often conflict with the scalability requirements of the Internet. This has motivated many proposals that try to offer service differentiation while keeping complexity low. This paper shares similar goals and proposes a simple scheme, BoundedRandomDrop (BRD), that supports multiple service classes. BRD focuses on loss differentiation, as although both losses and delay are important performance parameters, the steadily rising speed of Internet links is progressively limiting the impact of delay differentiation. BRD offers strong loss differentiation capabilities with minimal added cost. BRD does not require traffic profiles or admission controls. It guarantees each class losses that, when feasible, are no worse than a specified bound, and enforces differentiation only when required to meet those bounds. In addition, BRD is implemented using a single FIFO queue and a simple random dropping mechanism. The performance of BRD is investigated for a broad range of traffic mixes and shown to consistently achieve its design goals. This material is posted here with permission of the IEEE. Such permission of the IEEE does not in any way imply IEEE endorsement of any of the University of Pennsylvania's products or services. Internal or personal use of this material is permitted. However, permission to reprint/republish this material for advertising or promotional purposes or for creating new collective works for resale or redistribution must be obtained from the IEEE by writing to pubs-permissions@ieee.org. By choosing to view this document, you agree to all provisions of the copyright laws protecting it. Abstract-Today's Internet carries an ever broadening range of application traffic with different requirements. This has stressed its original, one-class, best-effort model, and has been one of the main drivers behind the many efforts aimed at introducing QoS. Those efforts have, however, experienced only limited success because their added complexity often conflict with the scalability requirements of the Internet. This has motivated many proposals that try to offer service differentiation while keeping complexity low. This paper shares similar goals and proposes a simple scheme, BoundedRandomDrop (BRD), that supports multiple service classes. BRD focuses on loss differentiation, as although both losses and delay are important performance parameters, the steadily rising speed of Internet links is progressively limiting the impact of delay differentiation. BRD offers strong loss differentiation capabilities with minimal added cost. BRD does not require traffic profiles or admission controls. It guarantees each class losses that, when feasible, are no worse than a specified bound,...

The Diels-Alder reactions between 2 equiv of (E,E)-1,4-bis(4-bromophenyl)-1,3-butadiene and 1,4-benzoquinone led to the formation of a key intermediate with all four 4-bromophenyl substituents cis to one another. The subsequent nickel-mediated homocoupling reactions then produced partially hydrogenated cycloparaphenylenes, including a molecule bearing two units of tetrahydro[6]cycloparaphenylene (4H[6]CPP) fused together through two 1,4-dimethoxybenzene units in an armchair (6,6)carbon nanotube-like connection. Similarly, two 6H[9]CPPs were connected through three 1,4-dimethoxybenzene units in an armchair (9,9)carbon nanotube-like arrangement. A bent 8H[12]CPP and a bent 12H[18]CPP, which were fused intramolecularly with two and three 1,4-dimethoxybenzene units, respectively, to create the bent structures, were likewise synthesized. A molecule containing a bent 8H[12]CPP fused to a 4H[6]CPP was likewise constructed. The structures of these partially hydrogenated CPPs were established by X-ray structure analysis, NMR spectroscopy, and additional independent synthetic pathways.

No abstract

We demonstrate a facile bottom-up growth of CuSCN -a widely used hole conducting material, in mesoscopic TiO 2 films by electrodeposition in the presence of TiO 2 compact layer. The profile-controlled growth of CuSCN in the nanopores of mesoscopic TiO 2 is realized by judiciously optimizing the electrolyte concentration and applied potential, so that the effective electron diffusion length in TiO 2 is much shorter than film thickness and the electrodeposition is strictly confined within very narrow region from the conducting substrate. The TiO 2 /CuSCN heterojunctions exhibit a pore filling ratio of ∼80% and show good rectifying properties, which is anticipated to be an important step forward to the facile fabrication of bulk heterojunction for nanostructured solar cells or 3D batteries.

No abstract