A novel oscillatory pressure sintering (OPS) process is reported to prepare highquality ceramics. The oscillatory pressure was applied at three stages (initial, intermediate, and final) during sintering process of zirconia ceramics for the first time. The microstructure of the samples prepared by OPS develops in a more homogeneous manner, leading to a higher final density, a smaller average grain size, and a narrower distribution of grain sizes compared with the samples prepared by conventional pressureless sintering (PS) and hot-pressing (HP) processes.Remarkably, the OPS samples was obtained at relatively lower heating temperature and less soaking time for 1300°C and 0.5 hours than the samples prepared by other two techniques at 1450°C and 1 hour. The current results suggest that OPS is an effective technique for preparing high-quality zirconia ceramics with low heating temperature and short sintering time, thus, it obviously reduces cost. K E Y W O R D S low sintering temperature, oscillatory pressure sintering, rapid densification, sintering stages, zirconia ceramics
Pure anorthite porous ceramics have been fabricated using γ‐Al2O3, CaCO3, and SiO2 as raw materials through foam‐gelcasting method. XRD, thermal analysis, SEM, and TEM were used to study the synthesis and grain growth of anorthite during the in situ process. The results indicated that the initiator (ammonium presulfate) took part in the chemical reaction to form CaSO4, which played an effective role during synthesis of anorthite. Besides, CaO and CaSiO2 were the other intermediate phase during synthesis. Anorthite first occurred at 1050°C, and it was the only phase after it sintered over 1260°C. With sintering temperature increasing from 1300°C to 1450°C, the large sphere pore wall got denser and the anorthite grains obviously showed platelike. It was deduced that the preferential growth of anorthite crystals was parallel to the (004) plane.
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