Semiconducting carbon nitride materials were successfully prepared via a thermal poly-condensation of dicyandiamide as a precursor at >500 1C. The resulting materials were investigated as metal-free catalysts for the activation of H 2 O 2 with visible light under mild conditions, using the decomposition of Rhodamine B (RhB) in aqueous solution as a model reaction. Results revealed that carbon nitride catalysts can activate H 2 O 2 to generate reactive oxy-radicals under visible light irradiation without employment of any metal additives, leading to the mineralization of the dye. Factors affecting the degradation of organic compounds are pH values and the concentration of H 2 O 2 . Recycling of the catalyst indicated no obvious deactivation during the entire catalytic reaction, indicating good (photo)chemical stability of metal-free polymeric carbon nitride photocatalysts for environmental purification. This study demonstrated a promising approach for the activation of green oxidant, hydrogen peroxide, by the newly-developed polymer photocatalysts for environmental remediation and oxidation catalysis.
Hot: Conjugated carbon nitride polymers (LCNs) are synthesized by hot‐fluid annealing in one pot. The LCNs possess a narrow band gap, have a complex nanostructure, and show enhanced photochemical performances. The described synthesis approach will allow the rational creation of a wide variety of polymeric carbon nitride semiconductors at low temperature in solutions, with control of structural complexity, electronic structure, and surface functionality.
E-banking has become one of the most popular methods of banking that has experienced a considerable expansion during the last few years. However, there is relative dearth of empirical studies examining the impact of e-banking on performance of banks. Though e-banking is gaining acceptance in Bangladesh, impact of e-banking on bank’s performance is yet to be established. This paper fills this gap. Using panel data of 13 banks over the period of 2003–2013, this study empirically investigated the impact of e-banking on the performance of Bangladeshi banks measured in terms of Return on Equity, Return on Assets and Net Interest Margin. Results from pooled ordinary least square analysis show that e-banking begins to contribute positively to banks’ Return on Equity with a time lag of two years while a negative impact was found in first year of adoption. Empirical findings of this study is of greater significance for the developing countries like Bangladesh because it will invoke the attention of the bank management and policy makers to pursue such policies to expand e-banking. This study also contributes to empirical literatures by reconfirming (or otherwise) findings of previous studies.
Ferrocene moieties were heterogenized onto carbon nitride polymers by a covalent -C=N- linkage bridging the two conjugation systems, enabling the merging of the redox function of ferrocene with carbon nitride photocatalysis to construct a heterogeneous Photo-Fenton system for green organocatalysis at neutral conditions. The synergistic donor-acceptor interaction between the carbon nitride matrix and ferrocene group, improved exciton splitting, and coupled photocatalytic performance allowed the direct synthesis of phenol from benzene in the presence of H2 O2 under visible light irradiation. This innovative modification method will offer an avenue to construct functionalized two-dimensional polymers useful also for other green synthesis processes using solar irradiation.
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