This study aimed to explore a test method for evaluating the effective cross-linking density of hydrogels. A guar gum–epichlorohydrin hydrogel (GEH) was prepared using guar gum (GG) as the raw material and epichlorohydrin (ECH) as the cross-linking agent. The thermal and mechanical properties, equilibrium swelling rate (ESR), water uptake (WU), and mass cross-linking degree of the hydrogels were assessed. Furthermore, the diffusion behavior of water molecules in the freeze-dried GEH was investigated. The experimental results showed the significance of the initial decomposition temperature (Ti) and final decomposition temperature (Tf) of the freeze-dried GEHs in determining the effective cross-linking density. The water uptake kinetics of the freeze-dried GEH was consistent with the linear fitting of the pseudo-second-order kinetic model and nonlinear fitting of the Fickian diffusion model, suggesting that chemisorption dominated the water absorption process in the GEH. Therefore, the effective cross-linking density of the hydrogels could be determined from the thermodynamic analysis and the diffusive behavior of water molecules in the gels. The thermal stability and water diffusion kinetics of the hydrogels were closely linked to the effective cross-linking density and pendant modification.
Progressive relaxation behavior of syndiotactic polystyrene (sPS) chains in sPS gel was detected in the course of melting via the application of intrinsic fluorescence and fluorescence anisotropy techniques. The melting process included a dissociative process of the network at lower temperature and a relaxation process from helix to worm-like chains at higher temperature. The dynamics of structural relaxation behavior was discovered by intrinsic fluorescence technique, and an abrupt bend emerged at 58 °C on the Arrhenius plot. At temperatures lower than 58 °C, only the dissociation of the helical structure existed and the rate of relaxation from helix to worm-like conformation was negligible. At temperatures higher than 58 °C, the transition from helical chain to worm-like chain was the rate-determining step. The intrinsic fluorescence technique demonstrated its practicability in detecting kinetic processes of sPS/chloroform gel in the course of melting.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.