Low sintering flue gas temperatures and large temperature fluctuations require the development of low-temperature and efficient SCR (selective catalytic reduction) catalysts suitable for the sintering process. It has been shown that modified Mn-Ce/TiO2 catalysts have good denitration capability and have potential commercial use. In this experiment, TiO2-loaded Mn and Ce SCR catalysts were prepared using the impregnation method, and a series of characterizations of the samples were carried out to illustrate the effect of the active material on the denitration efficiency. The kinetic analysis provides theoretical as well as data support for the subsequent optimization of the SCR catalysts. The results show that the denitration efficiency of the catalysts can reach 93.86% when the Mn content is 10% and the Ce content is 3%. The doping of active substances can increase the specific surface area, total pore volume and average aperture of the catalysts and improve the adsorption capacity of the catalysts.
The sulphide capacities of CaO-SiO 2 -Al 2 O 3 -MgO-TiO 2 -Fe t O slags with high titanium and Fe t O were measured by gas-slag equilibration technique to reveal the effect of slag composition and temperature on the sulphide capacities of slags. The results showed that sulphide capacities enhanced with the increase of temperature, basicity, Fe t O, and MgO contents, TiO 2 content increased first and then decreased in the range of 10 wt-% to 20 wt-%; the influence became negligible as the TiO 2 content exceeded 25 wt-%. MgO significantly increased the sulphide capacities of slag in the range of 6 wt-% to 8 wt-%, continued to increase the MgO content, and the increasing trend of Log C S became slowly; Fe t O content increased from 3 wt-% to 9 wt-%, sulphide capacities increased slowly, increased dramatically in the range of 9 wt-% to 15 wt-%. Meanwhile, comparing the optical basicity models found Zhang and Tsao's models are close to the experimentally determined values.
In response to the problem of rich vanadium-titanium magnetite (VTM) resources in China contrasting with low blast furnace utilization, a HIsmelt process for smelting VTM is proposed. The influence of the process parameters on smelting reduction is analysed under laboratory conditions by simulating smelting reduction. The results show that extending the reaction time reduces the FeO content in the slag by 15.34 wt-%, increasing the reaction temperature reduces the FeO content in the slag by 26.38 wt-%, and increasing the basicity reduces the FeO content in the slag by 11.26 wt-%. The control temperature for smelting VTM using the HIsmelt process is 1425°C, with a reduction time of 20-30 min, which is conducive to the transfer of vanadium to the molten iron and the enrichment of titanium in the slag. To ensure vanadium and titanium are efficiently utilized, a basicity control of 0.8 is appropriate.
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