The inherent quasi-brittleness of cement-based materials, due to the disorder of their hydration products and pore structures, present significant challenges for directional matrix toughening. In this work, a rigid layered skeleton of cement slurry was prepared using a simplified ice-template method, and subsequently flexible polyvinyl alcohol hydrogel was introduced into the unidirectional pores between neighboring cement platelets, resulting in the formation of a multi-layered cement-based composite. A toughness improvement of over 175 times is achieved by the implantation of such hard-soft alternatively layered microstructure. The toughening mechanism is the stretching of hydrogels at the nano-scale and deflections of micro-cracks at the interfaces, which avoid stress concentration and dissipate huge energy. Furthermore, this cement-hydrogel composite also exhibits a low thermal conductivity (around 1/10 of normal cement) and density, high specific strength and self-healing properties, which can be used in thermal insulation, seismic high-rise buildings and long-span bridges.
Traditional hard-grade asphalts for high-modulus asphalt concrete (HMAC) are produced by using natural hard-grade asphalt to modify matrix asphalts. However, natural hard-grade asphalts are scarce and expensive. To find a sustainable alternative, this study presented a method to synthesize hard-grade asphalts using phenol formaldehyde resin (PFR), hexamethylenetetramine (HMTA) and matrix asphalts. Infrared radiation (IR) spectra analysis and fraction analysis for the modifiers and synthesize asphalts show that asphalt molecules can be cross-linked into larger polymeric groups by the thermosetting phenol formaldehyde resin (TPFR) which is the reaction product of PFR and HMTA. This process increased the asphaltene and resin fraction in asphalt, thus transforming a matrix asphalt into hard grade. With the dosing combinations of 4% PFR/15~20% HMTA, 6% PFR/8~10% HMTA and 8% PFR/5~5.7% HMTA, dynamic modules of HMAC were 14,000~16,000 MPa, which satisfied the basic application requirements for HMAC. The rutting resistance of the new hard-grade asphalts with the above dosage combinations completely exceeds the traditional product using the Trinidad Lake asphalt as the raw material. Increasing the amount of PFR/HMTA can further improve the rutting resistance. However, to ensure the fatigue and cracking resistance of the HMAC can get a level like the traditional product, the dosages of HMTA should be controlled below 15%.
To clarify the intrinsic relationship between the mechanical properties of asphalt and its fraction composition, the SARA fraction composition and six macroscopic mechanical properties (critical cracking temperature (TCR), fatigue life (Nf), non-recoverable creep (Jnr3.2), penetration, ductility, and softening point) were investigated for 16 asphalt samples. Fraction contents of asphaltene and aromatic are strongly correlated with TCR and ductility (R2 > 0.92) that characterize the ability of asphalt to adapt to deformation at low and medium temperatures. Heavy fraction (asphaltene and resins) content is also strongly correlated with (R2 > 0.90) penetration and Jnr3.2 that characterize the resistance of the asphalt to overall deformation at medium and high temperatures. To express the changes in the four fractions simultaneously with one indicator, a statistic, average deviation of the fractions between the given asphalt and its original (marked σ), is introduced in this study to characterize the degree of asphalt aging based on the fraction changes. It normalizes the four simultaneous change indicators (percentage of SARA fractions) during asphalt aging into one indicator. This new indicator has a strong correlation with several mechanical performance indicators of asphalt, where it is strongly correlated with TCR (R2 > 0.90), ductility, and penetration, which are also well correlated with Jnr3.2 (R2 > 0.85), Nf (R2 > 0.75), and softening point (R2 > 0.75).
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