A dual-trans method to print the first functional liquid-metal circuit layout on poly(vinyl chloride) film, and then transfer it into a poly(dimethylsiloxane) substrate through freeze phase transition processing for the fabrication of a flexible electronic device. A programmable soft electronic band and a temperature-sensing module wirelessly communicate with a mobile phone, demonstrating the efficiency and capability of the method.
A systematic study is made of the effect of the nitrogen species on the performance of Li‐ion storage and the capacities of carbon‐based anodes in Li‐ion batteries (LIBs). Electrospun carbon nanofiber (CNF) films are fabricated for use as binder‐free electrodes using a polyacrylonitrile precursor. When the CNF films are subjected to carbonization, transformation occurs from an amorphous to a graphitic structure with associated reduction of nitrogen‐containing functional groups. The structural change strongly affects where the Li ions are stored in the CNF electrodes. It is revealed that Li ions can be stored not only between the graphene layers, but also at the defect sites created by nitrogen functionalization. The latter is mainly responsible for the widely reported improved electrochemical performance of LIBs due to N‐doping of carbon materials. An optimized carbonization temperature of 550 °C is identified, which gives rise to a sufficiently high nitrogen content and thus a high capacity of the electrode.
The mixed-metal-organic framework approach and a representative zirconium-metalloporphyrin framework (MOF-525) have been developed to create novel sulfur hosts and Li-S batteries. The different local environments at the centers of the porphyrin moieties in a series of MMOFs-MOF-525(2H), MOF-525(FeCl), and MOF-525(Cu)-have led to their different behaviors for the confinement of sulfur and thus Li-S batteries. The unique structure of MOF-525(Cu) has enabled each Cu(2+) site to offer two Lewis acidic sites, featuring it as a very powerful MOF host for the inclusion of sulfur and polysulfides. The S@MOF-525(Cu) cathode has demonstrated the best performance among all reported sulfur/MOFs composite cathode materials, with a reversible capacity of about 700 mAh/g at 0.5 C after 200 cycles.
As new generation functional materials, the recently emerging low-melting liquid metals have displayed many unconventional properties superior to traditional materials. Various methods, such as alloying, oxidizing, adding metals, or non-metallic materials and so on, have been developed to prepare desirable functional materials based on the gallium or more other metals. These methods could not only change the form of the materials, but also endow the original liquid metals with rather diversified performances, which have further expanded the application range of the low-melting liquid metals to meet various needs. This article aims to review and summarize on the fabrication methods, characteristics, and applications of the functional liquid metal materials. Furthermore, the future outlook in this field, including challenges, routes, and related efforts, has also been illustrated and interpreted.
BackgroundConventional ways of making bio-electrodes are generally complicated, expensive and unconformable. Here we describe for the first time the method of applying Ga-based liquid metal ink as drawable electrocardiogram (ECG) electrodes. Such material owns unique merits in both liquid phase conformability and high electrical conductivity, which provides flexible ways for making electrical circuits on skin surface and a prospective substitution of conventional rigid printed circuit boards (PCBs).MethodsFundamental measurements of impedance and polarization voltage of the liquid metal ink were carried out to evaluate its basic electrical properties. Conceptual experiments were performed to draw the alloy as bio-electrodes to acquire ECG signals from both rabbit and human via a wireless module developed on the mobile phone. Further, a typical electrical circuit was drawn in the palm with the ink to demonstrate its potential of implementing more sophisticated skin circuits.ResultsWith an oxide concentration of 0.34%, the resistivity of the liquid metal ink was measured as 44.1 µΩ·cm with quite low reactance in the form of straight line. Its peak polarization voltage with the physiological saline was detected as −0.73 V. The quality of ECG wave detected from the liquid metal electrodes was found as good as that of conventional electrodes, from both rabbit and human experiments. In addition, the circuit drawn with the liquid metal ink in the palm also runs efficiently. When the loop was switched on, all the light emitting diodes (LEDs) were lit and emitted colorful lights.ConclusionsThe liquid metal ink promises unique printable electrical properties as both bio-electrodes and electrical wires. The implemented ECG measurement on biological surface and the successfully run skin circuit demonstrated the conformability and attachment of the liquid metal. The present method is expected to innovate future physiological measurement and biological circuit manufacturing technique in a large extent.
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