The adhesion and cohesion between the coating layers and the ceramic honeycombs are usually one of the key issues in the preparation of high‐performance zeolite‐based/Monolith catalysts. In this work, we investigate the deposition of high‐efficiency Cu‐SAPO‐34 catalyst on a cordierite monolith with special focus on the impact of alumina binders on the structure, mechanical adhesion and cohesion, and catalytic performance of the monolithic catalyst. Two kinds of alumina nanoparticles, α‐alumina and γ‐alumina, have no significant impacts on the Cu‐SAPO‐34 crystal structure, micropore morphology and catalytic activity. But washcoating experiments showed that the mass loss rate of the coating was less and the loading of the catalyst was higher when α‐alumina was used as the binder. The reason of improving the adhesion and cohesion strength is the suitable thermal shrinkage, the uniform distribution and densification structure of α‐alumina. Furthermore, optimization of the coating formulation with α‐alumina as the binder has been performed. Finally, the catalyst prepared under the optimal conditions was tested by SCR and a maximum conversion rate of 97.4% was obtained. It was concluded that the use of the washcoating method with α‐alumina does not affect catalytic performance while it increases bonding strength between substrate and catalysts.
The effects of Nd2O3 addition on the crystallinities, microstructures, and properties of MgO–Al2O3–SiO2 (MAS) glass‐ceramics are investigated. The experimental results show that the addition of Nd2O3 allows complete sintering densification of the MAS at lower temperatures, and appropriate addition ratios increase the crystallinity, promote the formation of Indialite, improve the MAS microstructure, reduce the coefficient of thermal expansion, and optimize the dielectric properties. Ultimately, the best performance is achieved by adding 4 wt% Nd2O3 to the MAS sample and sintering at 1255 °C for 15 min. The bulk density is 2.51 g cm−3, εr = 6.50, tanδ = 1.96 × 10−3 (13 GHz), and CTE = 4.621 ppm °C−1.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.