The corrosion of carbon steel in aqueous media resulting in uniform corrosion, pitting corrosion and passivation was investigated on a laboratory scale. Recurrence quantification analysis was applied to short segments of electrochemical current noise measurements. These segments were converted to recurrence variables, which could be used as reliable predictors in a multilayer perceptron neural network model to identify the type of corrosion. In addition, an automated corrosion monitoring scheme is proposed, based on the principal component scores of the recurrence variables. This approach used the uniform corrosion measurements as reference data and could differentiate between uniform and non-uniform corrosion.
Corrosion of carbon steel under mineral wool insulation was studied using the electrochemical current noise (ECN) method. Intensities of corrosion were validated using gravimetry, and the form of corrosion confirmed using optical microscopy. The standard deviation of the current noise signal agreed with weight loss results and was demonstrated as a reliable indicator of the degree of corrosion under mineral wool insulation. Recurrence quantification analysis was used to extract feature variables from ECN signals, which were later used to develop a random forest model to identify the type of corrosion, i.e., uniform or localised corrosion. The trained model was successfully applied to predict the extent of localised corrosion associated with mineral wool insulation.
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