This report describes palladium catalyzed C-H glycosylation and retro Diels-Alder tandem reaction via structurally modified norbornadiene (smNBDs). The smNBDs was proposed to regulate the reactivity of aryl-norbornadiene-palladacycle (ANP) process, as...
A simple, mild, and efficient catalytic aminothiolation of terminal alkynes for the synthesis of both 2- and 3-substituted thiazolo[3,2-a]benzimidazoles is established upon catalysis with copper(i), in which complementary regioselectivities could be achieved by using sterically different phenanthroline-based ligands.
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