Surface nanobubbles have been presumed to lead to the experimental observation that liquid boiling often occurs at a much lower supersaturation than expected, yet no qualitative theory exists to explain how they participate in the process. Here, we report through a simple theoretical analysis on how the metastable nanobubbles nucleate the liquid-tovapor transition by serving as an intermediate phase. The appearance of metastable nanobubbles inhibits the shrink of the bubble nucleus and changes bubble nucleation into a multistep process. We show three possible mechanisms for heterogeneous nucleation starting from metastable surface nanobubbles: nucleation from pinned nanobubbles, nucleation via nanobubble depinning, and nucleation through nanobubble coalescence, each predicting a significant reduction in a nucleation barrier. The occurrence of a specific nucleation pathway of bubble nucleation depends on the detailed geometry of local substrate roughness. These results give insight into how the appearance of surface nanobubbles changes the nucleation mechanisms of liquid boiling.
In this paper, two-phase pressure drop data were obtained for boiling in horizontal rectangular microchannels with a hydraulic diameter of 0.55 mm for R-134a over mass velocities from 790 to 1122, heat fluxes from 0 to 31.08 kW/m2 and vapor qualities from 0 to 0.25. The experimental results show that the Chisholm parameter in the separated flow model relies heavily on the vapor quality, especially in the low vapor quality region (from 0 to 0.1), where the two-phase flow pattern is mainly bubbly and slug flow. Then, the measured pressure drop data are compared with those from six separated flow models. Based on the comparison result, the superficial gas flux is introduced in this paper to consider the comprehensive influence of mass velocity and vapor quality on two-phase flow pressure drop, and a new equation for the Chisholm parameter in the separated flow model is proposed as a function of the superficial gas flux . The mean absolute error (MAE ) of the new flow correlation is 16.82%, which is significantly lower than the other correlations. Moreover, the applicability of the new expression has been verified by the experimental data in other literatures.
In this paper experiments have been conducted to investigate the flow boiling and heat transfer characteristics in microchannels with three different surface wettability. Three types of microchannels with a super-hydrophilic surface (θ ≈ 0°), a hydrophilic surface (θ = 43°) and an untreated surface (θ = 70°) were prepared. The results show that the average heat transfer coefficient of a super-hydrophilic surface microchannel is significantly higher than that of an untreated surface microchannel, especially when the mass flux is high. The visualization of the flow patterns states that the number of bubble nucleation generated in the super-hydrophilic microchannel at the beginning of the flow boiling is significantly more than that in the untreated microchannel. Through detailed analysis of the experimental data, flow patterns and microchannel surface SEM images, it can be inferred that the super-hydrophilic surface microchannel has more active nucleation cavities, a high nucleation rate and a large nucleation number, a small bubble departure diameter and a fast departure frequency, thereby promoting the flow and heat transfer in the microchannel. In addition, through the force analysis of the vapor-liquid interface, the mechanism that the super-hydrophilic microchannel without dryout under high heat flux conditions is clarified.
With globalization and informatization, cross-border areas have become increasingly critical interactive spaces, experiencing rapid development and extensive changes in residents’ cross-border travel, constantly changing the spatial patterns of neighboring cities. However, existing studies lack in-depth discussions of the new spatiotemporal characteristics of human activities, spatial pattern evolution, and the driving factors behind them. Therefore, taking the Guangzhou-Foshan metropolitan area as a case, this paper focus on the analysis of the cross-city travel of residents in these border areas in 2019, and investigated the evolution of spatial patterns and the driving forces in the border area during 1985–2020. We found that, instead of the previous one-way attraction pattern caused by the spread of residence, a large number of cross-city trips for leisure and entertainment purposes emerged, and the one-way unbalanced flow, “Foshan to Guangzhou”, changed to two-way circulation. We also explore the scenario in which the travel behavior of urban dwellers in these two cities considerably interacts with the effect of urban structure to produce the observed mobility patterns. Second, we determined the spatial pattern of the Guangzhou-Foshan region from 1985 to 2020 to be on of spreading expansion, with Liwan District as the central core, connecting to several sub-centers. The cross-border area in the Guangzhou-Foshan region represented a compact, extremely high degree of integration and a well-matched functional space. Third, driven by the forces stemming from the planning guidelines and the improving transportation network construction in the border area, the growth points of the two cities continued to expand toward the borderline regarding integrated development, while the growth axis was mainly in the direction of the city border, urban arterial roads, and subway lines. We concluded with development suggestions for increasing travel interactions and optimizing spatial patterns to build a common vision of the whole Guangzhou-Foshan pattern of integration.
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