Despite increasing awareness of the need to trace the trajectory of innovation system research, so far little attention has been given to quantitative depiction of the evolution of this fast-moving research field. This paper uses CiteSpace to demonstrate visually intellectual structures and developments. The study uses citation analysis to detect and visualize disciplinary distributions, keyword co-word networks and journal cocitation networks, highly cited references, as well as highly cited authors to identify intellectual turning points, pivotal points and emerging trends, in innovation systems system research from 1975 to 2012.
Steam treatment is a hygrothermal method of potential industrial significance for improving the dimensional stability and durability of wood materials. The steaming results in different chemical and micromechanical changes in the nanostructured biocomposite that comprise a wood cell wall. In this study, spruce wood ( Picea abies Karst.) that had been subjected to high-temperature steaming up to 180 °C was examined, using imaging Fourier Transform Infrared (FT-IR) microscopy and nanoindentation to track changes in the chemical structure and the micromechanical properties of the secondary cell wall. Similar changes in the chemical components, due to the steam treatment, were found in earlywood and latewood. A progressive degradation of the carbonyl groups in the glucuronic acid unit of xylan and a loss of mannose units in the glucomannan backbone, that is, a degradation of glucomannan, together with a loss of the C═O group linked to the aromatic skeleton in lignin, was found. The development of the hygroscopic and micromechanical properties that occurred with an elevation in the steam temperature correlated well with this pattern of degradation in the constituents in the biocomposite matrix in the cell wall (hemicellulose and lignin).
After carbonization of bamboo nanocellulose aerogels in ammonia gas, the obtained nitrogen-doped carbon nanofiber (N-ACNF) aerogels with a tunable nanostructure were found to be ideal candidates for high-performance anodes in LIBs.
The objective of this paper was to investigate size distribution of micropores and mesopores within the wood cell walls between sapwood and heartwood by using nitrogen adsorption method and to find out implications for the biological durability and further processing such as in drying and preservation treatment. The pore shape, specific surface area and pore size distribution of Chinese fir (Cunninghamia lanceolata) were evaluated using the hysteresis loops, Brunauer-Emmett-Teller (BET) and density functional theories, respectively. Both the sapwood and heartwood exhibited slit-shaped pores with regard to the H3 type of hysteresis loop of the isotherm. However, more mesopores were found in the sapwood, while the micropores increased with a decrease in mesopores in the heartwood. Furthermore, the earlywood and latewood in the sapwood had a higher BET-specific surface area (2.088 and 1.255 m 2 g -1 , respectively) compared with the earlywood (1.058 m 2 g -1 ) and latewood (0.787 m 2 g -1 ) in the heartwood. This could be caused by an increase in depositions in the extractive that partly filled the mesopores of the heartwood cell walls during the transformation from the sapwood. Additionally, a larger amount of mesopores existed in the earlywood in comparison with the latewood in the sapwood. However, there was no significant difference in the amounts of the micropores and mesopores, when comparing the earlywood with the latewood in the heartwood.
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