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Nickel-iron/magnesium/aluminum bimetallic catalysts were prepared by the calcination and reduction of nickel-magnesium-iron-aluminum hydrotalcite-like compounds. Characterization suggests that, at iron/nickel≤0.5, both nickel and iron species are homogeneously distributed in the hydrotalcite precursor and incorporated into the Mg(Ni, Fe, Al)O periclase after calcination, giving rise to uniform nickel-iron alloy nanoparticles after reduction. Ni-Fe/Mg/Al (Fe/Ni=0.25) exhibits the best catalytic performance for the steam reforming of tar derived from the pyrolysis of biomass. It is suggested that the uniform nickel-iron alloy nanoparticles and the synergy between nickel and iron are responsible for the high catalytic performance. Moreover, the Ni-Fe/Mg/Al catalyst exhibits much better regenerability toward oxidation-reduction treatment for the removal of deposited coke than that of conventional Ni-Fe/α-Al2 O3 . This property can be attributed to the better regeneration of Ni-Fe alloy nanoparticles through the formation and reduction of Mg(Ni, Fe, Al)O.

Shear bands were generated under prescribed and controlled conditions in stainless steel . Hat-shaped specimens, deformed in a Hopkinson bar were used, yielding strain rates of approximately 104s-l and shear strains that could be varied between 1 and 100. Specimens recovered from the collapse of thick-walled cylinders were also investigated. Microstructural characterization was performed by electron backscattered diffraction (EBSD) with orientation imaging microscopy(OIM), and transmission electron microscopy (TEM). The shear-band thickness was approximately 8 jtim. This low-stacking fault energy alloy deforms, at the imposed strain rates (outside of the shear band), by planar dislocations and stacking fault packets, twinning, and occasional martensitic phase transformations at twin-twin intersections. EBSD reveals gradual lattice rotations of the grains approaching the core of the band. A [110] fiber texture (with the [110] direction perpendicular to both shear direction and shear plane normal) develops both within the shear band and in the adjacent grains. The formation of this texture, under an imposed global simple shear, suggests that rotations take place concurrently with the shearing deformation. This can be explained by compatibility requirements between neighboring deforming regions. EBSD could not reveal the deformation features at large strains because their scale was below the resolution of this technique. Transmission electron microscopy reveals a number of features that are interpreted in terms of the mechanisms of deformation and recovery/recrystallization postulated. They include the observation of grains with sizes in the nanocrystalline domain. The microstructural changes are described by an evolutionary model, leading from the initial grain size of 15 jum to the final submicronic (sub)grain size. Calculations are performed on the rotations of grain boundaries by grain-boundary diffusion, which is 3 orders of magnitude higher than bulk diffusion at the deformation temperatures. They indicate that the microstructural reorganization can take place within the deformation times of a few milliseconds.

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A copper(II)‐oxide‐based exhaust catalyst exhibits better activity than Pt‐ and Rh‐nanoparticle catalysts in NO remediation at 175 °C. Following theoretical design, the CuO catalyst is rationally prepared; CuO nanoplates bearing a maximized amount of the active {001} facet are arranged in interleaved layers. A field test using a commercial gasoline engine demonstrates the ability of the catalyst to remove NO from the exhaust of small vehicles.

Hydrogen was produced by methanol decomposition over cold-rolled foils of intermetallic compound Ni 3 Al which is known as an excellent high-temperature structural material. We found high catalytic activity and selectivity for methanol decomposition in flat cold-rolled Ni 3 Al foils. The catalytic activity was enhanced above 713 K by the spontaneous formation of fine Ni particles dispersed on carbon nanofibers during the reaction, resulting in high catalytic performance. The results demonstrate that the Ni 3 Al foils can be used both as catalyst precursors and as structural materials of microreactors for hydrogen production.

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