A comparison tool has been developed by mapping the global GPS total electron content (TEC) and large coverage of ionospheric scintillations together on the geomagnetic latitude/magnetic local time coordinates. Using this tool, a comparison between large‐scale ionospheric irregularities and scintillations is pursued during a geomagnetic storm. Irregularities, such as storm enhanced density, middle‐latitude trough, and polar cap patches, are clearly identified from the TEC maps. At the edges of these irregularities, clear scintillations appeared but their behaviors were different. Phase scintillations (σφ) were almost always larger than amplitude scintillations (S4) at the edges of these irregularities, associated with bursty flows or flow reversals with large density gradients. An unexpected scintillation feature appeared inside the modeled auroral oval where S4 were much larger than σφ, most likely caused by particle precipitations around the exiting polar cap patches.

Abstract. The concentrations and solubility of twelve trace elements in PM2.5 at Mt. Lushan, southern China, were investigated during the summer of 2011 and the spring of 2012. The average PM2.5 mass was 55.2 ± 20.1 μg m−3 during the observation period. Temporal variations of all trace elements including total and water-soluble fractions with several dust storm spikes in total fractions of Al and Fe were observed. The enrichment factor (EF) values were 1 order of magnitude higher for the water-soluble fractions versus the total fractions of trace elements. Four major emission sources, namely nonferrous metal mining and smelting (for Cr, As, Ba and parts of Zn), coal combustion (for Pb, Zn, Se, Cu and Mn), crustal materials (for Al and Fe) and municipal solid waste incineration (for Cd and Mo), were classified by principal component analysis (PCA). Trajectory cluster analysis and the potential source contribution function (PSCF) consistently identified the Yangtze River delta (YRD), the Pearl River delta (PRD), and the neighbouring provinces of Mt. Lushan as the major source regions and transport pathways for anthropogenic elements. Northern China was identified as a major source region for crustal elements. It should be noted that apart from the YRD, the area around Mt. Lushan has become the most significant contributor to the solubility of most trace elements. Element solubility can be partially determined by emission sources. However, enhanced solubility of trace elements corresponding to increased concentrations of sulfate after the occurrence of cloud events indicated significant effects of cloud processing on aerosol element dissolution. Metal particles mixed with sulfate in cloud droplet residues were further investigated through transmission electron microscopy (TEM) analysis. Irreversible alteration of particle morphology by cloud processing was confirmed to be highly responsible for the enhancement of trace element solubility. The findings from this study imply an important role of regional anthropogenic pollution and cloud processing in the evolution of aerosol trace element solubility during transport in the troposphere.

Using two B‐spline basis functions of degree 4 and the ionospheric scintillation data from a Global Positioning Satellite System (GPS) scintillation receiver at South Pole, we reproduced ionospheric scintillation indices for the periods of the six X‐class solar flares in 2013. These reproduced indices have filled the data gaps, and they are serving as a smooth replica of the real observations. In either event, these modeled scintillation indices are minimizing the geometrical effects between GPS satellite and the receiver. Six X‐class solar flares have been studied during the summer and winter months, using the produced scintillation indices based on the observations from the GPS receiver at South Pole and the in situ plasma measurement from the associated passing of Defense Meteorological Satellite Program. Our results show that the solar flare peak suppresses the scintillation level and builds time‐independent scintillation patterns; however, after a certain time from the solar flare peak, complicated scintillation patterns develop at high‐latitude ionosphere and spread toward the polar cap boundary region. Substantial consistency has been found between moderate proton fluxes and scintillation enhancement.

A method named total electron content (TEC) keogram is introduced for surveying the large-scale irregularities continuously in the polar ionosphere. The TEC keogram is developed from a movie of TEC maps along various meridian lines from the dayside to the nightside across the magnetic pole, trying to identify and track several types of ionospheric structures. Through two examples, a clear train of polar cap patches are identified from TEC keogram and confirmed by SuperDARN radar observations. The motion speed of these patches estimated from this tool agrees with SuperDARN radar measurements. Then, the motions of patches relative to the background convection through the whole polar cap are statistically studied for the first time. Moreover, the occurrence dependence of fully tracked patches on months, UT hours, and interplanetary magnetic field conditions is generally consistent with previous reports. These results suggest that the TEC keogram offers a power tool for continuous monitoring and studying of large-scale plasma irregularities in the polar ionosphere.