In this work, effects and mechanism analysis of samarium acetate and ytterbium acetate on enhancing the electrochemical corrosion performance of aluminum-based anode for aluminum-air batteries in 3.5 wt.% NaCl are studied by methods such as weight loss tests, electrochemical measurements, anode galvanostatic discharge tests and microscopic morphology analysis. The results show that samarium acetate and ytterbium acetate are ideal electrolyte additives, and exhibit obvious inhibitory effects on the self-corrosion of 7075 aluminum alloy. The optimal concentration is 200 mg/L. Moreover, corrosion inhibitors mainly reduce the self-corrosion speed of aluminum by suppressing the microcathodic reaction, thereby promoting the improvement of the discharge performance of aluminum-air batteries. Simultaneously, it is found that after mixing samarium acetate and ytterbium acetate in different proportions, the two rare earth salts have a mutual adjustment effect. By adding different rare earth salt components, the battery capacity densities of the anode are improved by 9.6% to 16.3%. Finally, a possible model is presented to illustrate the impact mechanism of different additives on the self-corrosion process and discharge performance of aluminum-air batteries.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.