Magnetoresistance is a change in the resistance of a material system caused by an applied magnetic field. Giant magnetoresistance occurs in structures containing ferromagnetic contacts separated by a metallic non-magnetic spacer, and is now the basis of read heads for hard drives and for new forms of random access memory. Using an insulator (for example, a molecular thin film) rather than a metal as the spacer gives rise to tunnelling magnetoresistance, which typically produces a larger change in resistance for a given magnetic field strength, but also yields higher resistances, which are a disadvantage for real device operation. Here, we demonstrate giant magnetoresistance across a single, non-magnetic hydrogen phthalocyanine molecule contacted by the ferromagnetic tip of a scanning tunnelling microscope. We measure the magnetoresistance to be 60% and the conductance to be 0.26G(0), where G(0) is the quantum of conductance. Theoretical analysis identifies spin-dependent hybridization of molecular and electrode orbitals as the cause of the large magnetoresistance.

Self-organized Co nanodots on a Au(111) surface have been surrounded by controlled Au rings that progressively cap the entire dots. The magnetic susceptibility of these dots has been measured in situ as a function of the Au coverage. The blocking temperature increases when the Co bilayer dots are surrounded by the first Au atomic layer and decreases with the subsequent capping. This result cannot be explained by interfacial anisotropy which is generally assumed to be the dominant term in the magnetic anisotropy of nanostructures. Using molecular dynamics simulations, we evidence that the large strain inside the Co clusters is the main driving force for the anisotropy changes during the Au encapsulation.

The magnetic susceptibility of self-organized two-dimensional Co nanodots on Au(111) has been measured as a function of their size in the 2-7 nm diameter range. We show that the activation energy for the thermal reversal displays a power law behavior with the dot volume. Atomic scale simulations based on the Heisenberg Hamiltonian show that this behavior is due to a deviation from the macrospin model for dot size as small as 3 nm in diameter. This discrepancy is attributed to finite temperature effects through the thermal excitation of spin-wave modes inside the particles.