Removing electrons from the CuO 2 plane of cuprates alters the electronic correlations sufficiently to produce high-temperature superconductivity. Associated with these changes are spectral-weight transfers from the high-energy states of the insulator to low energies. In theory, these should be detectable as an imbalance between the tunneling rate for electron injection and extraction—a tunneling asymmetry. We introduce atomic-resolution tunneling-asymmetry imaging, finding virtually identical phenomena in two lightly hole-doped cuprates: Ca 1.88 Na 0.12 CuO 2 Cl 2 and Bi 2 Sr 2 Dy 0.2 Ca 0.8 Cu 2 O 8+δ . Intense spatial variations in tunneling asymmetry occur primarily at the planar oxygen sites; their spatial arrangement forms a Cu-O-Cu bond-centered electronic pattern without long-range order but with 4 a 0 -wide unidirectional electronic domains dispersed throughout ( a 0 : the Cu-O-Cu distance). The emerging picture is then of a partial hole localization within an intrinsic electronic glass evolving, at higher hole densities, into complete delocalization and highest-temperature superconductivity.

In the high-transition-temperature (high-T(c)) superconductors the pseudogap phase becomes predominant when the density of doped holes is reduced. Within this phase it has been unclear which electronic symmetries (if any) are broken, what the identity of any associated order parameter might be, and which microscopic electronic degrees of freedom are active. Here we report the determination of a quantitative order parameter representing intra-unit-cell nematicity: the breaking of rotational symmetry by the electronic structure within each CuO(2) unit cell. We analyse spectroscopic-imaging scanning tunnelling microscope images of the intra-unit-cell states in underdoped Bi(2)Sr(2)CaCu(2)O(8 +) (delta) and, using two independent evaluation techniques, find evidence for electronic nematicity of the states close to the pseudogap energy. Moreover, we demonstrate directly that these phenomena arise from electronic differences at the two oxygen sites within each unit cell. If the characteristics of the pseudogap seen here and by other techniques all have the same microscopic origin, this phase involves weak magnetic states at the O sites that break 90 degrees -rotational symmetry within every CuO(2) unit cell.

The phase diagram of hole-doped copper oxides shows four different electronic phases existing at zero temperature. Familiar among these are the Mott insulator, high-transition-temperature superconductor and metallic phases. A fourth phase, of unknown identity, occurs at light doping along the zero-temperature bound of the 'pseudogap' regime 1 . This regime is rich in peculiar electronic phenomena 1 , prompting numerous proposals that it contains some form of hidden electronic order. Here we present low-temperature electronic structure imaging studies of a lightly hole-doped copper oxide: Ca 2−x Na x CuO 2 Cl 2 . Tunnelling spectroscopy (at energies |E|>100 meV) reveals electron extraction probabilities greatly exceeding those for injection, as anticipated for a doped Mott insulator. However, for |E|<100 meV, the spectrum exhibits a V-shaped energy gap centred on E=0. States within this gap undergo intense spatial modulations, with the spatial correlations of a four CuO 2 -unit-cell square 'checkerboard', independent of energy. Intricate atomic-scale electronic structure variations also exist within the checkerboard. These data are consistent with an unanticipated crystalline electronic state, possibly the hidden electronic order, existing in the zero-temperature pseudogap regime of Ca 2−x Na x CuO 2 Cl 2 .Scanning tunnelling microscopy (STM) has recently emerged as a suitable technique to search for 'hidden' electronic order in the copper oxides. Bi 2 Sr 2 CaCu 2 O 8+δ (Bi-2212) studies where high-transition-temperature (T c ) superconductivity (HTSC) was 2 suppressed to reveal the pseudogap have been especially fruitful. The prototypical study yielded a pseudogap-like conductance spectrum (V-shaped without coherence peaks) associated with a 'checkerboard' approximately four CuO 2 unit cells square of localdensity-of-states (LDOS) modulations surrounding vortex cores 2 . Similar phenomena were discovered throughout the sample above T c (ref.3), and within strongly underdoped nano-regions exhibiting pseudogap-like spectra 4 (see Fig. 1c). Underdoped Bi-2212 therefore shows a tendency towards checkerboard electronic modulations when HTSC is suppressed. However, it is unclear whether these checkerboard modulations in Bi-2212 represent a true electronic phase, because they exhibit [2][3][4] (1) a variety of dopingdependent incommensurate wavevectors, (2) very weak intensities, and (3) To search for electronic order hidden in the pseudogap while avoiding these uncertainties, we decided to study a simpler and less disordered copper oxide at lower doping and temperature. We chose Ca 2−x Na x CuO 2 Cl 2 (Na-CCOC), a material whose parent compound Ca 2 CuO 2 Cl 2 is a canonical Mott insulator 8 . Within its undistorted tetragonal crystal structure (Fig. 1b), all the CuO 2 planes are crystallographically identical. Sodium substitution for Ca destroys the Mott insulator state, producing first a nodal metal 9 in the zero-temperature pseudogap (ZTPG) regime, and eventually HTSC for x≥0. 10 (refs 10, 11). Crucially, Na-CCOC ...

The antiferromagnetic ground state of copper oxide Mott insulators is achieved by localizing an electron at each copper atom in real space (r-space). Removing a small fraction of these electrons (hole doping) transforms this system into a superconducting fluid of delocalized Cooper pairs in momentum space (k-space). During this transformation, two distinctive classes of electronic excitations appear. At high energies, the mysterious 'pseudogap' excitations are found, whereas, at lower energies, Bogoliubov quasi-particles-the excitations resulting from the breaking of Cooper pairs-should exist. To explore this transformation, and to identify the two excitation types, we have imaged the electronic structure of Bi(2)Sr(2)CaCu(2)O(8+delta) in r-space and k-space simultaneously. We find that although the low-energy excitations are indeed Bogoliubov quasi-particles, they occupy only a restricted region of k-space that shrinks rapidly with diminishing hole density. Concomitantly, spectral weight is transferred to higher energy r-space states that lack the characteristics of excitations from delocalized Cooper pairs. Instead, these states break translational and rotational symmetries locally at the atomic scale in an energy-independent way. We demonstrate that these unusual r-space excitations are, in fact, the pseudogap states. Thus, as the Mott insulating state is approached by decreasing the hole density, the delocalized Cooper pairs vanish from k-space, to be replaced by locally translational- and rotational-symmetry-breaking pseudogap states in r-space.

Fermi systems in the cross-over regime between weakly coupled Bardeen-Cooper-Schrieffer (BCS) and strongly coupled Bose-Einstein-condensate (BEC) limits are among the most fascinating objects to study the behavior of an assembly of strongly interacting particles. The physics of this cross-over has been of considerable interest both in the fields of condensed matter and ultracold atoms. One of the most challenging issues in this regime is the effect of large spin imbalance on a Fermi system under magnetic fields. Although several exotic physical properties have been predicted theoretically, the experimental realization of such an unusual superconducting state has not been achieved so far. Here we show that pure single crystals of superconducting FeSe offer the possibility to enter the previously unexplored realm where the three energies, Fermi energy e F , superconducting gap Δ, and Zeeman energy, become comparable. Through the superfluid response, transport, thermoelectric response, and spectroscopic-imaging scanning tunneling microscopy, we demonstrate that e F of FeSe is extremely small, with the ratio Δ=e F ∼ 1(∼ 0:3) in the electron (hole) band. Moreover, thermal-conductivity measurements give evidence of a distinct phase line below the upper critical field, where the Zeeman energy becomes comparable to e F and Δ. The observation of this field-induced phase provides insights into previously poorly understood aspects of the highly spin-polarized Fermi liquid in the BCS-BEC cross-over regime.BCS-BEC cross-over | Fermi energy | quasiparticle interference | iron-based superconductors | exotic superconducting phase S uperconductivity in most metals is well explained by the weak-coupling Bardeen-Cooper-Schrieffer (BCS) theory, where the pairing instability arises from weak attractive interactions in a degenerate fermionic system. In the opposite limit of Bose-Einstein condensate (BEC), composite bosons consisting of strongly coupled fermions condense into a coherent quantum state (1, 2). In BCS superconductors, the superconducting transition temperature is usually several orders of magnitude smaller than the Fermi temperature, T c =T F = 10 −5 -10 −4 , whereas in the BEC limit T c =T F is of the order of 10 −1 . Even in the high-T c cuprates, T c =T F is merely of the order of 10 −2 at optimal doping. Of particular interest is the BCS-BEC cross-over regime with intermediate coupling strength. In this regime the size of interacting pairs (∼ ξ), which is known as the coherence length, becomes comparable to the average distance between particles (∼ 1=k F ), i.e., k F ξ ∼ 1 (3-5), where k F is the Fermi momentum. This regime is expected to have the highest values of T c =T F = 0:1 − 0:2 and Δ=« F ∼ 0:5 ever observed in any fermionic superfluid.One intriguing issue concerns the role of spin imbalance: whether it will lead to a strong modification of the properties of the Fermi system in the cross-over regime. This problem has been of considerable interest not only in the context of superconductivity but also in ultraco...

Understanding the role of competing states in the cuprates is essential for developing a theory for high-temperature superconductivity. We report angle-resolved photoemission spectroscopy experiments which probe the 4a0 x 4a0 charge-ordered state discovered by scanning tunneling microscopy in the lightly doped cuprate superconductor Ca2-xNaxCuO2Cl2. Our measurements reveal a marked dichotomy between the real- and momentum-space probes, for which charge ordering is emphasized in the tunneling measurements and photoemission is most sensitive to excitations near the node of the d-wave superconducting gap. These results emphasize the importance of momentum anisotropy in determining the complex electronic properties of the cuprates and places strong constraints on theoretical models of the charge-ordered state.

The identity of the fundamental broken symmetry (if any) in the underdoped cuprates is unresolved. However, evidence has been accumulating that this state may be an unconventional density wave. Here we carry out site-specific measurements within each CuO 2 unit cell, segregating the results into three separate electronic structure images containing only the Cu sites [Cu(r)] and only the x/y axis O sites [O x (r) and O y (r)]. Phase-resolved Fourier analysis reveals directly that the modulations in the O x (r) and O y (r) sublattice images consistently exhibit a relative phase of π. We confirm this discovery on two highly distinct cuprate compounds, ruling out tunnel matrix-element and materials-specific systematics. These observations demonstrate by direct sublattice phaseresolved visualization that the density wave found in underdoped cuprates consists of modulations of the intraunit-cell states that exhibit a predominantly d-symmetry form factor.CuO 2 pseudogap | broken symmetry | density-wave form factor U nderstanding the microscopic electronic structure of the CuO 2 plane represents the essential challenge of cuprate studies. As the density of doped holes, p, increases from zero in this plane, the pseudogap state (1, 2) first emerges, followed by the high-temperature superconductivity. Within the elementary CuO 2 unit cell, the Cu atom resides at the symmetry point with an O atom adjacent along the x axis and the y axis (Fig. 1A, Inset). Intraunit-cell (IUC) degrees of freedom associated with these two O sites (3, 4), although often disregarded, may actually represent the key to understanding CuO 2 electronic structure. Among the proposals in this regard are valence-bond ordered phases having localized spin singlets whose wavefunctions are centered on O x or O y sites (5, 6), electronic nematic phases having a distinct spectrum of eigenstates at O x and O y sites (7,8), and orbital-current phases in which orbitals at O x and O y are distinguishable due to time-reversal symmetry breaking (9). A common element to these proposals is that, in the pseudogap state of lightly hole-doped cuprates, some form of electronic symmetry breaking renders the O x and O y sites of each CuO 2 unit cell electronically inequivalent.Electronic Inequivalence at the Oxygen Sites of the CuO 2 Plane in Pseudogap State Experimental electronic structure studies that discriminate the O x from O y sites do find a rich phenomenology in underdoped cuprates. Direct oxygen site-specific visualization of electronic structure reveals that even very light hole doping of the insulator produces local IUC symmetry breaking, rendering O x and O y inequivalent (10), that both Q ≠ 0 density wave (11) and Q = 0 C 4 -symmetry breaking (11, 12, 13) involve electronic inequivalence of the O x and O y sites, and that the Q ≠ 0 and Q = 0 broken symmetries weaken simultaneously with increasing p and disappear jointly near p c = 0.19 (13). For multiple cuprate compounds, neutron scattering reveals clear intraunit-cell breaking of rotational symmetry (14,15...

Majorana quasiparticles (MQPs) in condensed matter play an important role in strategies for topological quantum computing [1-5] but still remain elusive.Vortex cores of topological superconductors may accommodate MQPs that appear as the zero-energy vortex bound state (ZVBS) [6,7]. An iron-based superconductor Fe(Se,Te) possesses a superconducting topological surface state [8][9][10][11] that has been investigated by scanning tunneling microscopies to detect the ZVBS [12,13]. However, the results are still controversial [12,13]. Here, we performed spectroscopic-imaging scanning tunneling microscopy with unprecedentedly high energy resolution to clarify the nature of the vortex bound states in Fe(Se,Te). We found the ZVBS at 0±20 µeV suggesting its MQP origin, and revealed that some vortices host the ZVBS while others do not. The fraction of vortices hosting the ZVBS decreases with increasing magnetic field, while chemical and electronic quenched disorders are apparently unrelated to the ZVBS. These observations elucidate the conditions to achieve the ZVBS, and may lead to controlling MQPs. * tadashi.machida@riken.jp † hanaguri@riken.jp arXiv:1812.08995v2 [cond-mat.supr-con]