Reflectance measurements and organic petrography were used to study altered organic matter in the dolomitic Middle Jurassic Beddiane sequence hosting the Beddiane lead–zinc deposit. Organic matter occurs in the lower dolostone units of the formation where zinc sulfide mineralization prevails. The upper units, where lead sulfide mineralization is dominant, contain lesser amounts of organic matter. The organic matter in the Beddiane sequence consists of macerals, amorphous kerogen, and solid bitumen, inertinite and vitrinite are ubiquitous. The amount of exinite increases toward mineralized areas but the ratio exinite/kerogen remains constant. Two types of vitrinite are considered on the basis of their reflectance: Vt1 with low reflectance values (0.3–0.5%) and Vt2 with higher values (0.7–1.25%). The ratio Vt1/Vt2 increases and the reflectance values for Vt1 decrease toward the zinc-prevailing units, Organic matter associated with the mineralization exhibits features such as oxidation halos and desiccation cracks, together with a low-fluorescent exinite. The association of the kerogen content, the trend in reflectance values, and the alteration features of the Mississippi Valley-type Beddiane deposit support the hypothesis that the regional flow of hot brines associated with the mineralization process was the cause of anomalous heating, that the occurrence of exinite maceral and its associated gas played a role in the ore deposition, and that the new chemical equilibrium reached by the zinc-dominant host rock after ore deposition is responsible for the suppressed reflectance values within and near the ore deposits.
The organic matter (OM) sampled in 15 oil exploration wells and 102 outcrops of Cambrian-Ordovician rocks in the St. Lawrence Lowlands consists of zooclasts (chitinozoans, graptolites, and scolecodonts) and solid bitumen (mainly pyrobitumen). The reflectance of pyrobitumen, transformed in vitrinite-equivalent (Ro-Std-B), indicates that the upper part of the platform sequence is mature (condensate zone) in the Québec area, but overmature in the Montréal area.The platform is divided into three domains based on optical texture of OM and types of bitumen: domain 1, south of Montréal, contains a highly reflecting and coked pyrobitumen showing alteration rims; domain 3, east of Trois-Rivières, contains low-reflecting, late solid bitumen commonly associated with oil impregnations; domain 2, located midway, contains a pyrobitumen with moderate reflectance and, locally, fine mosaic texture. The thermal maturation in the autochthonous sequences of the St. Lawrence Lowlands and in the Appalachian allochthons increases from the north-east toward the south-west and in the direction of the Appalachian belt. In wells, the gradient of Ro-Std-B with depth decrease from the autochthonous zone toward the Appalachian belt, and is inversely related with thickness of the sequences. Isoreflectance values parallel the outline of the Chambly–Fortierville Syncline in the central and eastern parts of the basin. Consequently, thermal maturation predates folding. Reflectance jumps observed between the Lowlands and the first Appalachian overthrusts, and observed when crossing Logan's Line, demonstrate that the maximum burial of Appalachian sequences predates the tectonic transport. The Ro-Std-B in allochthonous zones shows higher values in the St-Francis River cross-section than in structural equivalent units of the Québec area. Therefore the increase of thermal maturation observed from the northeast toward the southwest, in the St. Lawrence Lowlands, is also developed in the Appalachian allochthonous units. A post-Taconic regional thermal event explains this similarity in both autochthonous and allochthonous sequences, with the sequences of the Connecticut Valley – Gaspé Synclinorium being the most thermally mature.Zones of highest thermal maturation, locally observed in the Montréal area, are explained by (i) hydrothermal activity (Ro-Std = 3–4%), accounted for by sulfate and sulfide mineralization (Ba, Zn, Pb) and by (ii) contact metamorphism, related to alkaline intrusions (Ro-Std-B = 13%). The contact metamorphism is restricted to aureoles less than 5 km wide around the Monteregian alkaline intrusions, but the hydrothermal alteration, apparently not related to contact metamorphism, covers an area of 10 km around mineralized domains.
Seventeen genera of algae, seven of which are codiaceans, and twenty-six species (three of which are new) occur in the reef, reefoid, and lagoonal facies of the Silurian Sayabec Formation in the Lake Matapedia region.
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